Photostable yellow composite pigments and process for their prep

Compositions: coating or plastic – Coating or plastic compositions – Metal-depositing composition or substrate-sensitizing...

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106193R, 106289, 106300, 524190, 534739, C08L 108, E09D 1100

Patent

active

045239533

ABSTRACT:
There are described organic-inorganic ternary composite pigments consisting of 70%-90% by weight of an inorganic binary titanium dioxide/aluminum hydrate component and, from 10% to 30% by weight, of a co-precipitated organic component consisting of an organic dye, containing in its structure at least one carboxylic and/or sulphonic acid function, having the formula: ##STR1## wherein R.sub.1 is selected from the group consisting of NO.sub.2 --SO.sub.3 H and --COOH; R.sub.2 is selected from the group consisting of NO.sub.2, --SO.sub.3 H, alkyl and alkoxyl; R.sub.3 is selected from the group consisting of H, halogen and alkyl; R.sub.4 and R.sub.5 are each selected from the group consisting of H, halogen, alkyl and alkoxyl; R.sub.6 is selected from the group consisting of H, halogen and alkoxyl; and wherein the --COOH and/or --SO.sub.3 H group of dye (I) is salified with metal cations.
The pigments are obtained by co-precipitation acidifying an aqueous solution and/or dispersion of acid dye (I) in sodium aluminate, in the presence of TiO.sub.2, maintained at 40.degree.-80.degree. C. and at pH=9.5-10.5, by then treating it with any aqueous solution of an alkaline-earth (Ca, Ma, Al, Ba, Sr) salt or of Mn or Zn.

REFERENCES:
patent: 1086155 (1914-02-01), Geldermann et al.
patent: 1788300 (1931-01-01), Huismann et al.
patent: 3520869 (1970-07-01), Stocker et al.
patent: 4084983 (1978-04-01), Bernhardt et al.

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