Photopolymerizable organopolysiloxane/silane compositions

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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260 18S, 428438, 428439, 428443, 428447, 428449, 428452, 428523, 428526, 528 17, 528 18, 528 30, 528 32, 528901, C08F 246

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active

042908698

ABSTRACT:
Photopolymerizable, liquid, storage stable organopolysiloxanes having viscosities of from 60 mPa.s to 2,000 mPa.s at 25.degree. C., are prepared by reacting (i) an .alpha.,.omega.-dihydroxydiorganopolysiloxane oil having a viscosity ranging from about 70 to 500 mPa.s at 25.degree. C., with (ii) a silane having the formula Z(G)SiR.sub.a (Q).sub.3-a wherein Z is CH.sub.2 .dbd.C(R')--COO-- or HS--, and further wherein the symbols R, which may be the same or different, are methyl, ethyl, n-propyl, vinyl or phenyl, R' is hydrogen or methyl, the symbols Q, which may be the same or different, are methoxy, ethoxy, n-propoxy, .beta.-methoxyethoxy and, when any two are taken together, the divalent radical --O--(CH.sub.3).sub.2 --C(CH.sub.3).sub.2 --O--, G is a linear or branched chain alkylene radical having from 1 to 8 carbons, and a is a number ranging from 0 to 2; and with the molar ratio of the hydroxyl functions comprising the oil (i) to the Q radicals comprising the silane (ii) ranging from 0.1 to 0.95. Such organopolysiloxanes are useful, e.g., release coating compositions.

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patent: 4039504 (1977-08-01), Homan et al.
patent: 4039505 (1977-08-01), Homan et al.
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