Photopolymerizable composition, photoinitiator mixture and curin

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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1562755, B23B 2716, C08J 710

Patent

active

045294917

ABSTRACT:
The present invention relates to a photopolymerizable composition comprising a polymerizable, polyethylenically unsaturated compound, benzil and/or fluorenone, a specific biphenyl ketone such as para-phenyl benzophenone, and a reducing agent such as a tertiary amine. The present composition permits rapid and complete curing. Moreover, in the photopolymerization of compounds sensitive to air inhibition non-tacky surfaces are obtained. The effect observed is based on a synergism between the present photoinitiators. The advantages of the invention are most manifest in curing relatively thick layers of materials.

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patent: 3933682 (1976-01-01), Bean
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patent: 4024297 (1977-05-01), Gruber
patent: 4054682 (1977-10-01), Kuesters et al.
patent: 4054721 (1977-10-01), Cordes
patent: 4077858 (1978-03-01), Costanza
patent: 4442022 (1984-04-01), van der Hauw et al.
J. Oil Col. Chem. Assoc., 1976, 59, pp. 157-165.
J. Chem. Soc. (C), 1969, pp. 2203-2207.

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