Chemistry of inorganic compounds – Sulfur or compound thereof
Patent
1992-03-24
1992-11-10
Straub, Gary P.
Chemistry of inorganic compounds
Sulfur or compound thereof
4235611, 423 37, 430398, 430400, 430455, C01B 1700
Patent
active
051621061
ABSTRACT:
A process is disclosed for recovering silver sulfide from a spent photographic fixer solution, which contains silver. The process is particularly suited for treating the fixer solution in a manner which enables recycling of the solution giving rise to considerable reduction in cost of fixer solution and reduced environmental pollution. The process comprises introducing a hydrosulfide reagent into the fixer solution, which contains silver, to precipitate silver sulfide while maintaining pH and thiosulfate levels in the fixer to allow for reuse. The precipitate is isolated from the fixer solution to remove silver thereby and hence enable recycling of the fixer solution.
REFERENCES:
patent: 483972 (1892-10-01), Whitehead
patent: 1446405 (1923-02-01), Thomas
patent: 1527942 (1925-02-01), Weisberg
patent: 2748000 (1956-05-01), Mader
patent: 3082079 (1963-03-01), Bulloch et al.
patent: 3634088 (1972-01-01), Colley
patent: 3709660 (1973-06-01), Urban
patent: 3825425 (1974-07-01), Heilmann
patent: 3832453 (1974-08-01), Slovonsky
patent: 3907568 (1975-09-01), Shirasu et al.
patent: 4127639 (1978-11-01), Piret
patent: 4755453 (1988-07-01), Kunda
patent: 5055382 (1991-10-01), Long et al.
patent: 5085836 (1992-02-01), Booker
Morana, "Silver Recovery From Waste of Film by Burning", Precious Metals, 1981, pp. 369-377.
Holleman, "Lehrbuch Der Anorganischen Chemie", 1971, p. 288.
"Effective Competing Equilibria On The Solubility of Precipitates," pp. 101-102.
Patent Abstracts of Japan, vol. 12, No. 258.
"Recovering Silver From Photographic Materials," No. J-10, 1972.
W. Kunda, "Processing of Photographic Spent Solution by Chemical Method," Jun., 1983.
Chemical Abstracts, 109(26)240579h Oct. 31, 1987.
Chemical Abstracts 109(16)132602b Dec. 15, 1986.
Chemical Abstracts 109(7)53943k Feb. 1988.
Chemical Abstracts 106(22)186253v Dec. 1986.
Chemical Abstracts 102(16)140720j Aug. 31, 1984.
Chemical Abstracts 101(6)46221e May 10, 1984.
Chemical Abstracts 101(4)26712n May 1, 1984.
Chemical Abstracts 100(14)107101u Oct. 1983.
Chemical Abstracts 95(24)211809v Jun. 1981.
W. Kunda et al., "Recovery of Silver From X-ray Film," Jun. 1985.
M. L. Schreiber, "Present Status of Silver Recovery in Motion-Picture Laboratories," Mar., 1965.
R. LaPerle, "The Removal of Metals From Photographic Effluent by Sodium Sulfide Precipitation," SMPTE Journal, vol. 85, Apr. 1976.
D. Branch, "Silver Recovery Methods for Photoprocessing Solutions," Journal of Imaging Technology, vol. 14, pp. 160-166, 1988.
Etsell Thomas H.
Kunda Wasyl
Straub Gary P.
The Governors of the University of Alberta
Vanoy Timothy C.
LandOfFree
Photographic fixer regeneration does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Photographic fixer regeneration, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Photographic fixer regeneration will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2291097