Photographic elements containing magenta couplers and process fo

Radiation imagery chemistry: process – composition – or product th – Color imaging process – Using identified radiation sensitive composition in the...

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430555, G03C 7384

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active

053506677

ABSTRACT:
A photographic element contains a light-sensitive silver halide layer having associated therewith a coupler which is a pyrazolone compound with a coupling-off substituent at the -4-position, said compound having the formula: ##STR1## wherein each R.sup.1 is independently a substituted or unsubstituted alkylsulfonyl or arylsulfonyl group; each R.sup.2 and R.sup.3 is independently a substituent; R.sup.4, R.sup.5, and R.sup.6 are independently hydrogen or substituted or unsubstituted alkyl groups; m and n are independently 0 or 1 but both are not 0; x1 and x2 are independently 0 to 5; and y is 0 to 3; provided that each of R.sup.3, R.sup.4, R.sup.5, and R.sup.6 is selected such that the calculated log P of the thiophenol corresponding to the substituent at the 4-position of the pyrazolone is at least 4. The photographic element provides an improved combination of low continued coupling together with a magenta hue exhibiting a long wavelength of maximum absorption.

REFERENCES:
patent: 4463085 (1984-07-01), Mutsui et al.
patent: 4853319 (1989-08-01), Krishnamurthy et al.
patent: 4994359 (1991-02-01), Morigaki et al.
patent: 5250405 (1993-10-01), Merkel et al.
patent: 5256528 (1993-10-01), Merkel et al.

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