Photographic element and coating composition

Radiation imagery chemistry: process – composition – or product th – Radiation sensitive product – Silver compound sensitizer containing

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430539, 430614, 430640, 2523152, 396 6, G03C 134

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active

056143605

ABSTRACT:
A photographic element and an aqueous coating composition for providing a layer to a photographic element are disclosed. The coating composition comprises gelatin in a concentration greater than about 6% by weight, and a palladium complex having the structure: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, and R.sup.8 are independently selected from hydrogen, alkyl, alkenyl, aryl or alkaryl, the alkyl, alkenyl, aryl, or alkaryl optionally being substituted with a hydroxy, sulfonate, amino or ammonium group; and wherein any two of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, and R.sup.8 can be bonded to form a ring;
Z.sup.1 and Z.sup.2 independently represent the number of carbon atoms necessary to form a 5 or 6 membered ring, inclusive of palladium, wherein the carbon atoms may be substituted with hydrogen, sulfonate, alkyl, alkenyl, aryl or alkaryl, the alkyl, alkenyl, aryl, or alkaryl optionally being substituted with a hydroxy, halogen, sulfonate, amino or ammonium group; and
n is -2 to 4.

REFERENCES:
patent: 2448060 (1946-07-01), Smith et al.
patent: 2472627 (1949-06-01), Smith et al.
patent: 2552229 (1951-05-01), Stauffer et al.
patent: 2566245 (1951-08-01), Trivelli et al.
patent: 2598079 (1952-05-01), Stauffer et al.
patent: 4242430 (1980-12-01), Hara et al.
patent: 4623615 (1986-11-01), Yokoyama et al.
patent: 4892808 (1990-01-01), Harbison et al.

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