Radiation imagery chemistry: process – composition – or product th – Radiation sensitive product – Identified backing or protective layer containing
Reexamination Certificate
1999-10-05
2001-08-07
Schilling, Richard L. (Department: 1752)
Radiation imagery chemistry: process, composition, or product th
Radiation sensitive product
Identified backing or protective layer containing
C430S533000, C430S536000, C430S534000, C428S315900, C428S483000
Reexamination Certificate
active
06270950
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to imaging materials. In a preferred form, it relates to base materials for photographic reflective paper.
BACKGROUND OF THE INVENTION
In the formation of color paper it is known that the base paper has applied thereto a layer of polymer, typically polyethylene. This layer serves to provide waterproofing to the paper, as well as providing a smooth surface on which the photosensitive layers are formed. The formation of a suitably smooth surface is difficult requiring great care and expense to ensure proper laydown and cooling of the polyethylene layers. One defect in prior formation techniques is caused when an air bubble is trapped between the forming roller and the polyethylene which will form the surface for casting of photosensitive materials. This air bubble will form a pit that will cause a defect in the photographic performance of photographic materials formed on the polyethylene. It would be desirable if a more reliable and improved surface could be formed at less expense.
In color papers there is a need for providing color papers with improved resistance to curl. Present color papers will curl during development and storage. Such curl is thought to be caused by the different properties of the layers of the color paper as it is subjected to the developing and drying processes. Humidity changes during storage of color photographs lead to curling. There are particular problems with color papers when they are subjected to extended high humidity storage such as at greater than 50% relative humidity. Extremely low humidity of less than 20% relative humidity also will cause photographic papers to curl. Image curl creates viewing problems as light is not uniformly reflected from the surface of an image causing the image to appear less sharp. It would be desirable if a reflective photographic image had less image curl such that the ambient viewing light was more uniformly reflected.
In photographic papers the polyethylene layer also serves as a carrier layer for titanium dioxide and other whitener materials as well as tint materials. It would be desirable if the colorant materials rather than being dispersed throughout the polyethylene layer could be concentrated nearer the surface of the layer where they would be more effective photographically.
In U.S. Pat. No. 5,866,282 (Bourdelais et al.), a composite photographic material with laminated biaxially oriented polyolefin sheets has been proposed. While this invention does provide a solution to the sensitivity of photographic paper to humidity, it uses standard photographic base paper whose roughness is replicated on the surface of the imaging element. Traditional cellulose paper base utilized in this invention has a particularly objectionable roughness in the spatial frequency range of 0.30 to 6.35 mm. In this spatial frequency range, a surface roughness average greater than 0.50 micrometers can be objectionable to consumers. Visual roughness greater than 0.50 micrometers in usually referred to as orange peel. It would be desirable if a base with a roughness average less than 0.50 micrometers could be utilized with laminated biaxially oriented sheets.
During the manufacturing process for photographic papers, while the laminated photographic support is being emulsion coated and slit, the laminated structure is subjected to various forces in manufacturing that will cause delamination of the polypropylene sheet from the paper. The delamination may be a result of bonding layer failure to either the base paper or the polypropylene sheet. Also, when the photographic paper is being processed and finished at photofinishers, the laminated structure is also subjected to various forces in both the wet and dry state. Furthermore, when the photographic paper is kept for years by the final customer, the laminated structure is subjected to forces created by temperature and humidity changes that could cause delamination of the biaxially oriented polyolefin sheets from the cellulose paper base. Delamination of the biaxially oriented sheet from the paper during manufacturing will result in the product being wasted thus increasing the cost of manufacture. Delamination of the biaxially oriented sheet from the paper at either the photo finishing operation or in the final customer format will result in a loss in the appearance of the image and the reduction of the commercial value of the photograph. It would be desirable if a melt extruded bonding adhesive could prevent delamination of biaxially oriented sheets from the base paper during manufacture of a laminated imaging support and in the final customer format.
Prior art photographic support materials typically utilize melt extruded polyethylene to waterproof the paper during the wet processing of images during image the image development process. The gelatin based light sensitive silver halide emulsion generally adheres well to the polyethylene layer during manufacturing and wet processing of images. It would be desirable if a biaxially oriented sheet contained an integral bonding layer to provide emulsion adhesion during emulsion coating and the wet processing of images during the image development step.
Commercially available photographic paper typically has a single color logo identifying the manufacturer of the photographic paper. This logo is applied to the backside of the photographic paper and is generally printed on the base paper before the polyethylene coating is applied. The present product is practically limited to a single color because the present production machines are limited by cost and space limitations to a single color press for the printing of indicia onto the back of the base paper. It would be desirable if a low cost method of applying multiple colors to the back side of photographic paper were available.
Present photographic papers generally being constructed of polyethylene coated cellulose paper, can be easily damaged, torn or abraded as images are viewed by consumers over the lifetime of an image. It would be desirable if a photographic paper support were more tear resistant, offering the consumer a image that is tougher than current photographic images.
Prior art photographic reflective paper use white pigments, typically TiO
2
and blue colorants to provide a white support and improve image sharpness during exposure by preventing the exposure light from reaching the paper fibers where the light is scattered and reflected back to the imaging layers. It has been found that while the TiO
2
does improve image sharpness and does provide a white support, TiO
2
below the imaging layers corrupts the dye hue angle of photographic dyes, changing the dye hue angle away from the perceptually preferred hue angle of the dyes. It would be desirable if a support material has the image sharpness, opacity and whiteness of prior art color papers without the use of white pigments in the support.
PROBLEM TO BE SOLVED BY THE INVENTION
There remains a need for a more effective base with improved surface, better tear resistance, improved image curl and better maintained dye hue angle.
SUMMARY OF THE INVENTION
It is an object of the invention to provide improved photographic papers.
It is another object to provide a base material for photosensitive images that will have improved surface smoothness.
It is a further object to provide a photographic element with improved dye hue angle.
It is another object to provide tear resistant photographic paper.
It is a further object to provide a photographic reflective paper that may have multiple color indicia on the back of photographic images.
These and other objects of the invention are accomplished by a photographic element comprising a laminated base wherein said base comprises a voided polyester sheet having laminated thereto a biaxially oriented polyolefin sheet on the bottom of said polyester sheet and a biaxially oriented polyolefin sheet laminated to the top of said polyester sheet.
ADVANTAGEOUS EFFECT OF THE INVENTION
The invention provides an improved photographic support. It particularly pro
Aylward Peter T.
Bourdelais Robert P.
Camp Alphonse D.
Eastman Kodak Company
Leipold Paul A.
Schilling Richard L.
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