Photoelectrolysis of water by solar radiation

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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136 89AC, 204278, 204192R, C25B 104, H01L 3104

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active

040111490

ABSTRACT:
Photoelectrolysis of water by solar radiation to produce hydrogen is achieved using semiconducting thin film electrodes. The cell comprises (a) an electrode comprising at least one thin film semiconducting layer disposed on a substrate, each layer having a bandgap which ranges from about 1.3 to 4.0 eV; (b) a counter-electrode; (c) an electrolyte disposed between the thin film semiconducting electrode and the counter-electrode; (d) external bias means between the electrode for biasing the electrode with from 0 to about 1 V; and (e) means for collecting hydrogen produced.

REFERENCES:
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patent: 3925212 (1975-12-01), Tchernev
J. Keeney et al., "Electricity From Photosensitization of Thanium," Nature, vol. 253, No. 5494, pp. 719-720 (Feb. 1975).
S. N. Paleocrassas, "Photocatalytic Hydrogen Production: A Solar Energy Conversion Alternative?," Solar Energy, vol. 16, pp. 45-51 (1974).
F. Mollers et al., "On the Origin of the Photocatalytic Deposition of Noble Metals on TiO.sub.z," J. Electrochem. Soc., vol. 121, pp. 1160-1167 (1974).
K. L. Hardee et al., "Semiconductor Electrodes," J. Electrochem. Soc., vol. 122, pp. 739-742 (1975).
A. Fujishima et al., "Electrochemical Photolysis of Water At a Semiconductor Electrode," Nature vol. 238, pp. 37-38 (1972).

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