Photoelectrochromic generator and display device

Chemistry: electrical current producing apparatus – product – and – Deferred action type – Responsive to light

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350357, H01M 636, G02F 101

Patent

active

043650104

ABSTRACT:
A photoelectrochromic display device having a semiconductor electrode, and a counterelectrode made of a selected metallic material is presented. The electrode and counterelectrode are immersed in an aqueous solution containing heptyl viologen. The device is usable as a display device, as a storage battery, and as an alternating current photoelectric generator. As a display device, the cell requires only two leads rather than multiple leads and complicated electrical addressing and decoding required for most multi-character displays.

REFERENCES:
patent: 3950077 (1976-04-01), Jasinski
patent: 4242423 (1980-12-01), Hada
J. Bruinink et al, "The Voltammetric Behavior of Some Viologens at SuO.su Electrodes", J. Electrochem. Soc., vol. 125, pp. 1397-1401 (1978).
C. J. Shoot et al, "New Electrochemical Memory Display", _Appl. Phys. Lett., vol. 23, pp. 64-65 (1973).
M. Yamana, "New Photoelectrochemical Display", Appl. Phys. Lett., vol. 29, pp. 570-571 (1976).
H. T. von Dam et al, "Electrochemically Generated Colored Films of Insoluble Viologen Radical Compounds", J. Electrochem. Soc., vol. 121, pp. 1555-1558 (1974).
C. Daul et al, "Transient Processes in Photogalvanic Cells-Part III, the Alternating Current Photogalvanic Cell", J. Electroanal. Chem., vol. 125, pp. 307-313 (1981).
T. Inoue et al, "Photoelectrochemical Imaging Processes Using Semiconductor Electrodes", Chem. Lett., pp. 1197-1200 (1978).
T. Inoue et al, "Photoelectrochemical Characteristics of Photo-Electrochemical Imaging System . . . ", J. Electrochem. Soc., vol. 127, pp. 1582-1588 (1980).
T. Inoue et al, "A New Method of Reproducible Photoelectrochemical Imaging Employing a Semiconductor Photoelectrode", Japan J. Appl. Phys., vol. 18, pp. 2177-2178 (1979).
B. Reichman et al, "Semiconductor Electrodes-XXV, The p-GaAs/Heptyl Viologen System Photoelectrochemical Cells & Photoelectrochromic Displays", J. Electro Chem. Soc., vol. 127, pp. 333-338 (1980).
Chem. Abstracts, vol. 92, 205961k (1980).

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