Photoelectrochemical cells having functions as a solar cell and

Chemistry: electrical current producing apparatus – product – and – Deferred action type – Responsive to light

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H01M 630, H01L 3104

Patent

active

049160354

ABSTRACT:
Photoelectrochemical cells comprising a positive electrode comprised of an n-type conductive semiconductor and a compound capable of reversibly intercalating or deintercalating metal atoms or ions, an ion conductive solid electrolyte layer, a negative electrode, and current collectors for the positive and negative electrodes. The intercalating or deintercalating compound is a Chevrel compound or vornite. The photoelectrochemical cell serves as both solar and secondary cells. Various cell constructions are also described including a multi-layered structure and a two-cell construction.

REFERENCES:
patent: 4119768 (1978-10-01), Bayard
patent: 4235955 (1980-11-01), Sammells et al.
"Photo-Electrochemical Studies on Intercalation and Semiconducting Intercalation Compounds", by Helmut Tributsch; Solid State Ionics 9 & 10 (1983)41-58; North-Holland Publishing Company.
"Photoelectrochemical Energy Conversion Involving Transition Metal d-States and Intercalation of Layer Compounds", by Helmut Tributsch; Structure and Bonding 49; Springer-Verlag, Berlin-Heidelberg (1982).

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