Photochromic spirooxazine polysiloxanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Chalcogen in the nitrogen containing substituent

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544 71, 252586, 351163, 359241, 359242, 430340, C07F7/08;7/10;7/18

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active

059051485

ABSTRACT:
Polysiloxane copolymers containing both photochromic and lightstabilizing groups with enhanced UV-fatigue resistance can be used as coatings for devices with variable optical density, including lenses, glazing, textiles and the like, to provide light-sensitive darkening effects. The photochromic groups are spironaphtooxazine groups and the lightstabilizing groups are hindered amine light stabilizing (HALS) groups.

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Crano, J.C. et al., "Spiroxazines and their use in photochromic lenses.", Applied Photochromic Polymer Systems, pp. 31-79 (1992).
Krongauz, V., "Photochromic liquid crystal polymers.", Applied Photochromic Polymer System, pp. 121-173 (1992).
Krongauz, V., "Environmental effects on organic photochromic systems.", chp. 21, pp. 793-821 (1990).

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