Photochromic spiro(indoline)naphthoxazine compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Chalcogen in the nitrogen containing substituent

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359647, 351162, 351163, 523106, 523135, 524 90, 524 97, G02B 2700, C07D26500, C07D29500

Patent

active

054059585

ABSTRACT:
Described are novel reversible photochromic spiro(indoline) naphthoxazine compounds of improved photocolorability that may be graphically represented by the formula, ##STR1## In preferred embodiments, R.sub.1 is allyl, alkoxyalkyl, and alkyl; each R.sub.2 is alkyl or alkoxy; R.sub.3 and R.sub.4 are alkyl; R.sub.5 is alkoxycarbonyl; and R.sub.6 is hydroxy, alkoxy, or carboxy, e.g., acetoxy. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the naphthoxazine compounds or combination thereof with complementary photochromic compounds, e.g., naphthopyran or benzopyran compounds, are also described.

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