Photochemically stable mid and deep ultraviolet pellicles

Stock material or miscellaneous articles – Composite – Of addition polymer from unsaturated monomers

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428522, 428524, 428527, 350 16, 350164, 350582, 430 5, B32B 2708

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active

050081560

ABSTRACT:
Mid and deep ultraviolet light transmitting pellicles for protecting photomasks from particle contamination during a projection printing process. The pellicles are manufactured from polyglycidyl-methacrylate-ethacrylate copolymer, from polyvinyl butyral polymer or from nitrocellulose. The polyvinyl butyral pellicle is sandwiched between two layers of an antireflective coating of poly-1H, 1H Pentadecafluorooctyl methacrylate or poly-1H, 1H Pentadecafluorooctyl acrylate. The nitrocellulose pellicle includes two double layers of antireflective material with the first double layer positioned on one side of the nitrocellulose layer and comprising a layer of the thermoplastic phenolic resin novalac and a layer of either poly-1H, 1H Pentadecafluorooctyl methacrylate or poly-1H, 1H Pentadecafluorooctyl acrylate. The second double layer is positioned on the other side of the nitrocellulose layer and comprises a layer of novolac and a layer of either poly-1H, 1H Pentadecafluorooctyl methacrylate or poly-1H, 1H Pentadecafluorooctyle acrylate.

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Ron Hershel, Pellicle Protection of Integrated Circuit (IC) Masks, SPIE, vol. 275, Semiconductor Microlithography VI, 1981, 23-28.
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F. W. Billmeyer, Jr., Textbook of Polymer Science, pp. 468-470 (John Wiley and Sons, Inc., 2nd ed., 1971).

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