Photochemical preparation of plutonium pentafluoride

Details Photochemical preparation of plutonium pentafluoride Photochemical preparation of plutonium pentafluoride

1977-12-20

1987-06-02

Terapane, John F.

Chemistry of inorganic compounds

Radioactive

Transuranium compound

423 3, 20415722, C01G 5600, B01D 5900

Patent

active

046702393

ABSTRACT:
The novel compound plutonium pentafluoride may be prepared by the photodissociation of gaseous plutonium hexafluoride. It is a white solid of low vapor pressure, which consists predominantly of a face-centered cubic structure with a.sub.o =4.2709.+-.0.0005 .ANG..

REFERENCES:
patent: 4082633 (1978-04-01), Eerkens
patent: 4522794 (1985-06-01), Hochel et al.
Brewer, L. et al. "The Higher Fluorides of Plutonium", UCRL-633 (Mar. 20, 1950).
Steindler, M. J. "Laboratory Investigations in Support of Fluid Bed Fluoride Volatility Processes Pt. II. The Properties of Plutonium Hexafluoride", ANL-653.
Trevorrow, L. E. et al. "The Thermal Decomposition of Plutonium Hexafluoride", J. Phys. Chem. 65:398-403, 1961.
Tsujimura, S. et al. "Thermal Decomposition of Plutonium Hexafluoride", J. Nucl. Sci. and Tech. 9:534-7, 1972.

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