Photochemical dimerization and functionalization of alkanes, eth

Details Photochemical dimerization and functionalization of alkanes, eth Photochemical dimerization and functionalization of alkanes, eth

1986-11-10

1988-02-16

Niebling, John F.

Chemistry: electrical and wave energy

Processes and products

Processes of treating materials by wave energy

2041576, 20415774, 2041579, 20415792, 20415793, 20415814, C07C 276, C07C 2900, C07C 3100, C07C 4101

Patent

active

047253428

ABSTRACT:
The space-time yield and/or the selectivity of the photochemical dimerization of alkanes, ethers, primary alcohols and tertiary silanes with Hg and U.V. light is enhanced by refluxing the substrate in the irradiated reaction zone at a temperature at which the dimer product condenses and remains condensed promptly upon its formation. Cross-dimerization of the alkanes, ethers and silanes with primary alcohols is disclosed, as is the functionalization to aldehydes of the alkanes with carbon monoxide.

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