Photochemical decarboxylation of a metal salt of an alpha-hydrox

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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B01J 1912

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active

044500599

ABSTRACT:
A process is provided for the photochemical decarboxylation of a metal salt of an alpha-hydroxy carboxylic acid to form the corresponding alcohol wherein the alpha-hydroxy carboxylic acid metal salt is exposed to light in the absence of a photosensitizing agent.

REFERENCES:
patent: 4264421 (1981-04-01), Bard et al.
patent: 4303486 (1981-12-01), Bard et al.
Euler et al., Biochemische Zeitschrift, vol. 51, pp. 97-106, 1913.
Baudisch, Biochemische Zeitschrift, vol. 103 (1920), pp. 59-62.
Muller, Biochemische Zeitschrift, vol. 178 (1926), pp. 77-78.
Burns, JACS, vol. 51 (1929), pp. 3,165-3,171.
Bard, Science, vol. 207 (1980), pp. 139-144.

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