Photobase generator and curable composition

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property or radiation sensitive... – Radiation sensitive composition or product or process of making

Reexamination Certificate

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C430S919000, C430S921000, C430S923000, C430S280100, C430S270100, C522S031000, C522S033000, C522S034000, C522S038000, C522S039000, C522S045000, C522S050000, C522S054000, C522S063000, C522S168000, C564S282000, C564S284000, C564S287000, C564S288000, C564S289000, C568S042000, C568S043000, C568S044000, C568S058000

Reexamination Certificate

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11050740

ABSTRACT:
The photobase generator of the invention is represented by the following formula 1:wherein Ar, R, A+and X−are as defined in the specification. Since the photobase generator of the formula 1 absorbs ultraviolet lights of relatively long wavelength and is photolyzed to generate a strong base efficiently, a composition containing the photobase generator and an episulfide compound is easily cured by polymerization under ultraviolet irradiation.

REFERENCES:
patent: 2759971 (1956-08-01), Cutler et al.
patent: 6635195 (2003-10-01), Wanigatunga et al.
Cutler, Royal A. et al., “New antibacterial agents. 2- Acylamino 1-(4-hydrocarbonylsulfonylphenyl)-1, 3-propanediols and related compounds” Journal of the American Chemical Society, vol. 74, 5475-81, 1952.
Tachi, Hideki et al., “Photochemical reactions of quaternary ammonium dithiocarbamates as photobase generators and their use in the photoinitiated thermal crosslinking of poly(glycidyl methacrylate)” Journal of Polymer Science, Part A: Polymer Chemistry; vol. 39(9), 1329-1341, 2001.
Shirai, Masamitsu et al., “Photoacid and photobase generators: chemistry and applications to polymeric materials” Progress in Polymer Science, vol. 21(1), 1-45, 1996.
European Search Report mailed Apr. 25, 2005, for EP 05 10 0487.

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