Photoactivatable two-stage protective groups for the...

Combinatorial chemistry technology: method – library – apparatus – Tag or label specially adapted for combinatorial chemistry...

Reexamination Certificate

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C536S025320, C435S068100, 53

Reexamination Certificate

active

07737089

ABSTRACT:
The present invention relates to a process for synthesizing biopolymers by stepwise assembly from protected synthesis building blocks which carry two-stage protective groups. The two-stage protective groups are activated by a first illumination step and eliminated by a subsequent chemical treatment step. Photoactivatable components which considerably speed up the activation process via intramolecular triplet sensitizers or/and have fluorescence properties are used. The two-stage protective groups can be used in particular within the framework of quality control.

REFERENCES:
patent: 2004/0197851 (2004-10-01), Guimil et al.
patent: 101 22 357 (2002-11-01), None
patent: WO 00/66259 (2000-11-01), None
patent: WO 02/20150 (2002-03-01), None
patent: WO 02/62815 (2002-08-01), None
patent: WO 03/04510 (2003-01-01), None
patent: WO 03/004510 (2003-01-01), None
patent: WO 2004/058392 (2004-07-01), None
Happ et al., “New Trityl-Based Protecting Groups with a Mild Two-Step Removal”,Nucleosides&Nucleotides, vol. 7, No. 5/6, 1988 pp. 813-816.

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