Photo-electric chemical apparatus using carbon cluster electrode

Chemistry: electrical and wave energy – Apparatus – Electrolytic

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204294, 205340, 205630, 136291, 429111, H01L 310256

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active

057230293

ABSTRACT:
A photo-electric chemical apparatus comprising an electrolyte, a first electrode having an n-type semiconductor member disposed to be in touch with the electrolyte and a second electrode having a carbon cluster member disposed to be in touch with the electrolyte. The first and second electrodes are short-circuited and irradiated with a light beam to thereby generate oxygen and hydrogen. The first electrode is a laminated member consisting of a light transmitting glass, a transparent conducting layer and an n-type semiconductor layer. The second electrode is a laminated member consisting of a light transmitting glass, a transparent conducting layer and a carbon cluster thin film.

REFERENCES:
patent: 3925212 (1975-12-01), Tchernev
patent: 4090933 (1978-05-01), Nozik
patent: 4643817 (1987-02-01), Appleby
patent: 5171373 (1992-12-01), Hebard
patent: 5320723 (1994-06-01), Kawakami
Patent Abstracts of Japan; vol. 018, No. 161 (E-1526), 17 Mar. 1994; JP-A-05 335614 (Idemitsu Kosan Co. Ltd), 17 Dec. 1993.
Fujishima et al., "Electrochemical Photolysis of Water at a Semiconductor Electrode", Nature, vol. 238, Jul. 7, 1972, pp. 37-38.
A.J. Nozik, "Photochemical diodes", Applied Physics Letters, vol. 30, No. 11, Jun. 1, 1977, pp. 567-569.
Miller et al., "Photoelectrochemical Behavior of C.sub.60 Films", J. Am. Chem. Soc., vol. 11, No. 16, 1991, pp. 6291-6293, no month available.
Tsubomura, "Photoelectrochemistry and Energy Conversion", 1980, pp. 180-182, no month available.

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