Phosphorylation with monomeric metaphosphates

Details Phosphorylation with monomeric metaphosphates Phosphorylation with monomeric metaphosphates

1992-07-20

1994-08-02

Owens, Terry J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Phosphorus esters

558106, 558107, 558108, 558109, 8181, 8194, 8196, C07F 902

Patent

active

053347412

ABSTRACT:
Solid substrates with free hydroxyl groups are phosphorylated by thermolysing a solution of phosphoramidate of the formula ##STR1## in the presence of the substrate, whereby metaphosphate is generated which phosphorylates the substrate.

REFERENCES:
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Ermolenko, et al., SU,A,610,892, Derwent Publications Ltd., London, GB, May 15, 1978, Abstract.
Louis D. Quin et al.; Metaphosphate and Metaphosphomic Anhydride Formation by Thermolysis of 5,6-Oxaphosphabicyclo[2.2.2]octenes: Electrophilic .alpha.-Substitution on a Pyrrole; pp. 3389-3390; J. Am. Chem. Soc. 1985, 107.
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Hamer; Studies in Phosphorylation; Part XXVI; The Mechanism of Phosphorylation by Monoesters of Phosphoramidic Acid; pp. 46-52; J. Chem. Soc. (London), 1965.
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V. M. Clark et al.; Studies in Phosphorylation. Part XXVIII. The Formation of Pyrophosphates fron Phosphoramidate Monoesters; pp. 5509-5513; J. Chem. Soc. (London), 1965.

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