Phosphorus substituted metallocene compounds for olefin...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S165000, C526S172000, C502S103000, C502S152000, C502S155000, C556S022000, C556S053000

Reexamination Certificate

active

11078588

ABSTRACT:
This invention relates to a metallocene compounds represented by formula:whereinM is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom;E is an indenyl ligand that is substituted with a PR2group in the two position of the indenyl ligand, where each R is, independently a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl substituent, and additionally, E may be substituted with 0, 1, 2, 3, 4, 5 or 6 Rnwhere each Rnis, independently, a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent, and optionally, two or more adjacent Rnsubstituents may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent;A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E or as X;each X is, independently, an univalent anionic ligand, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.

REFERENCES:
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patent: 6191241 (2001-02-01), Starzewski et al.
patent: 98/07760 (1998-02-01), None
Gobley et al., “Some New exo,exo-Bis(isodicyclopentadienyl)titanium and -zirconium Dichloride Derivatives: Synthesis, Characterization, and Evaluation as Propene Polymerization Catalysts”, Organometallics, 1998, 17, 4897-4903.
Leyser et al., “Phosphonium-Bridged Alkali and Alkaline-Earth Metallocene Complexes”, Organometallics, 1998, 17, 2155-2161.
Schaverien et al., “Phosphorus-bridged metallocenes: New homogeneous catalysts for the polymerization of propene”, Journal of Molecular Catalysis A: Chemical 128(1998), 245-256.
Alt et al., “PPh-bridged metallocene complexes of the type (C13H8-PPh-C13H8)MC12(M=Zr, Hf)”, Journal of Organometallic Chemistry, 568, (1998) 127-131.
Shin et al., “Phosphorus-Bridgedansa-Metallocene Complexes of Titanium, Zirconium, and Hafnium: The Syntheses and Structures of [PhP(C5Me4)2]MX2and [Ph(E)P(C5Me4)2]MX2(E = O, S, Se) Derivatives”, Organometallics, 1999, 18, 6-9.
Häp et al., “Dichloro[bis(η3-2,4-cyclopentadien-l-yl)alkylphosphan]zirconium: PR(C5H4)2ZrCl2; R = Me, Et,1Pr,1Bu”, Z. Naturforsch. 54 b, 482-486 (1999).
Shin et al., “CationicAnsa-Zirconocene and Hafnocene Derivatives of a Monoanionic Phosphonium-Bridged Bis(permethylcyclopentadienyl) Ligand: Synthesis and Structural Characterization of {[Me2P(C5Me4)2]MCl2}+(M = Zr, Hf) and {[Me2P(C5Me4)2]ZrMe2}+”, Organometallics, 2000, 19, 5155-5159.
Reetz et al., “A New Class of Chiral Diphosphines Having Planar Chirality”, Tetrahedron Letters 40 (1999) 4977-4980.

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