Phosphorus, nitrogen, bromin containing polymers and process for

Bleaching and dyeing; fluid treatment and chemical modification – Chemical modification of textiles or fibers or products thereof – Cellulose fibers

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8192, 106 15FP, 252 81, 260 294R, 260 294UA, 260 457P, 260 296MP, 260 296MN, 427390, 428921, C08G 5124, D06M 1332, D06M 1338

Patent

active

039544001

ABSTRACT:
Textile treating compositions containing the elements phosphorus, nitrogen, and bromine and the processes for imparting flame resistance to organic fibrous materials have been prepared. This is accomplished by impregnating the textile treating compositions consisting of (1) tris(hydroxymethyl)phosphine mixed with nitrogenous compounds containing at least two members of the group hydrogen and methylol radicals (--CH.sub.2 OH) attached to trivalent nitrogen atoms, or (2) soluble methylol phosphine adducts which contain one or more methylol phosphine radicals (P--CH.sub.2 OH) prepared by reacting tris(hydroxymethyl)phosphine with an amide or amine which contains one or more hydrogens attached to a trivalent nitrogen with an organic bromine containing material with at least 10% bromine in the form of bromine atoms attached to carbon atoms, in proportions selected so that generally the phosphorus contained in structures of the group (--CH.sub.2).sub.3 P amounts to a small portion of the total weight of the mixture, and heating to cause insolubilization in or on the fibrous structure.

REFERENCES:
patent: 3698854 (1972-10-01), Donaldson et al.
patent: 3883463 (1975-05-01), Jin et al.

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