Phosphorous containing polymers as carriers for transition metal

Details Phosphorous containing polymers as carriers for transition metal Phosphorous containing polymers as carriers for transition metal

1981-12-21

1983-06-07

Lee, Lester

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

From phenol, phenol ether, or inorganic phenolate

525538, 528167, 528168, 528169, C08G 7904

Patent

active

043872085

ABSTRACT:
Synthesis of new (lithiophenoxy)phosphazene high polymers is described whin polymers such as poly(dichlorophosphazene) are used as the starting material to prepare poly(organophosphazenes) by reaction thereof with sodium para-bromophenoxide. Poly(organophophazenes) thus obtained are used in a metal-halogen exchange reaction with n-butyllithium. The lithio derivatives thus obtained are used as reactive intermediates for the synthesis of polymers of formulas [NP(OC.sub.6 H.sub.4 X-p).sub.x (OC.sub.6 H.sub.4 Br)y].sub.n and [NP(OC.sub.6 H.sub.4 Li-p).sub.x (OPh).sub.y ].sub.n, where X is PPh.sub.2, PPh.sub.2 C.sub.4 H.sub.9.sup.+ Br.sup.-, SnPh.sub.3, AuPPh.sub.3, or COOH.

REFERENCES:
patent: 4182834 (1980-01-01), Hergenrother
patent: 4218556 (1980-08-01), Hergenrother
patent: 4221904 (1980-09-01), Hergenrother
patent: 4242493 (1980-12-01), Chen et al.
patent: 4247680 (1981-01-01), Hergenrother
patent: 4267311 (1981-03-01), Elefritz, Jr.

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