Phosphorous containing ligands for metathesis catalysts

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

Reexamination Certificate

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C556S023000, C502S155000, C548S101000, C526S171000, C585S511000, C585S514000, C585S523000

Reexamination Certificate

active

10518716

ABSTRACT:
The use of a phosphorus containing Ligand as a Ligand for a metathesis catalyst in a catalysed metathesis reaction wherein the phosphorus containing Ligand is a heterocyclic organic compound with a ligating phosphorus atom as an atom in the heterocyclic ring structure of the heterocyclic organic compound. The invention also relates to a metathesis catalyst such a phosphorus containing Ligand and to a metathesis reaction using the catalyst.

REFERENCES:
patent: 1 109 787 (1968-04-01), None
patent: WO 00 58322 (2000-10-01), None
patent: WO 02 14248 (2002-02-01), None
Fürstner; “Olefin Metathesis and Beyond”; Angew. Chem. Int. Ed. 2000, vol. 39, 2000, pp. 3012-3043, (2000).
Scholl, et al.; “Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene Ligands”; Organic Letters, vol. 1, No. 6, pp. 953-956, (1999).
Trnka, et al.; “The Development of L2X2Ru=CHR Olefin Metathesis Catalysts: An Organometallic Success Story”; Accounts of Chemical Research; vol. 34, No. 1, pp. 18-29, (2001).

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