Phosphoric acid group-containing polymer electrolyte...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S274000, C526S286000, C526S287000, C526S317100, C526S318200, C526S304000, C526S320000, C526S323100, C526S328500, C428S311110, C442S110000, C429S006000, C429S006000, C429S249000, C429S254000

Reexamination Certificate

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10399628

ABSTRACT:
The invention relates to solid polyelectrolyte membranes and processes for their production. As solid polyelectrolyte materials, there have been known fluoropolymers which have perfluoroskeletons and side chains bearing sulfonic acid groups and heat-resistant resins which have hydrocarbon skeletons and contain alkylsulfonic acid or alkylphosphoric acid groups introduced thereto. The fluoropolymers are excellent in heat resistance and chemical resistance but have the problem of being expensive, while the heat-resistant resins have the problem of being poor in chemical resistance. Further, solid polyelectrolyte materials having higher electric conductivities have been desired. With the purpose of providing solid polyelectrolyte membranes having satisfactorily high electric conductivities and being excellent in heat resistance and chemical resistance and processes for producing the membranes, solid polyelectrolyte membranes are made from resins bearing both phosphoric acid groups and sulfonic acid groups which resins are obtained by copolymerizing a monomer bearing in the molecule a phosphoric acid group and an ethylenically unsaturated bond with a monomer bearing in the molecule a sulfonic acid group and an ethylenically unsaturated bond.

REFERENCES:
patent: 48-4547 (1973-01-01), None
patent: 57-115426 (1982-07-01), None
patent: 64-22932 (1989-01-01), None
patent: 7-50170 (1995-02-01), None
patent: 7-296634 (1995-11-01), None
patent: 9-87570 (1997-03-01), None
patent: 9-110982 (1997-04-01), None
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patent: 11-354140 (1999-12-01), None
patent: 2000-11755 (2000-01-01), None
patent: 2001-181352 (2001-03-01), None
patent: 2001-114834 (2001-04-01), None
patent: 2003-138088 (2003-05-01), None
Daisuke Inagaki et al., “Phosphonic-Sanki wo yuusuru Shinki Proton Dendou-sei Koubunshi no Gousei to Tokusei Hyouka (I)”, Koubunshi Gakkai Yokoushuu (1999), vol. 48, No. 3, 414.
Full English translation of Daisuke Inagaki et al., “Synthesis And Evaluation of Novel Proton-Conducting Polymers Containing Phosphoric Ester (I),” Polymer Preprints, Japan vol. 48, No. 3 p. 414 (1999).
Daisuke Inagaki et al., “Synthesis And Evaluation of Novel Proton-Conducting Polymers Containing Phosphoric Ester (III),” Polymer Preprints, Japan vol. 49, No. 4, p. 751 (2000) w/English translation.
Takeshi Kobayashi, et al., “Preparation of Thermally Stable Proton Conducting Polymer II,” Polymer Preprints, Japan vol. 42, No. 7, pp. 2490-2492 (1993) w/English translation.
Hisashi Ishikawa, et al., “Preparation and Electrical Properties of Proton Conducting Polymers,” Polymer Preprints, Japan vol. 43, No. 3, pp. 735-736 (1994) w/English translation.
Takeshi Kobayashi, et al., “Preparation of Thermally Stable Proton Conductive Polymer,” Polymer Preprints, Japan vol. 42, No. 3, p. 730 (1993) w/English translation.
Full English translation of JP 48-4547 A.
Full English translation of JP 7-50170.
Full English translation of JP 64-22932 A.
Full English translation of JP 2000-11755 A.

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