Phosphole and diphosphole ligands for catalysis

Details Phosphole and diphosphole ligands for catalysis Phosphole and diphosphole ligands for catalysis

1999-10-08

2000-10-24

Vollano, Jean F

Organic compounds -- part of the class 532-570 series

Organic compounds

Phosphorus containing

564 12, C07F 950

Patent

active

061370126

ABSTRACT:
Novel reactions used to prepare phosphole and bisphosphole compounds are detailed. Novel phosphole compounds and metal coordination compounds of phosphole and bisphosphole compounds are also provided. These metal coordination compounds are useful as catalysts for the polymerization or olefins with carbon monoxide and for the polymerization of acrylic monomers.

REFERENCES:
patent: 2577208 (1951-12-01), Reppe et al.
patent: 4818810 (1989-04-01), Drent
patent: 4835250 (1989-05-01), Drent
CA:121:57586 abs of Phosphorus, Sulfur Silicon and Relat Elem by Brunet et al 85(1-4) pp 207-215, 1993.
CA:109:73592 abs of J Organomet Chem by Deschamp et al 332(1-2) pp 141-152, 1987.
Schenk, W. A., "Reaktive Arsen-Heterocyclen", Journal of Organometallic Chemistry, vol. 467, No. 1, 67-73, 1994.
Doherty, S. et al., "Palladium Complexes of C2-, C3-, and C4-Bridged Bis(phospholyl) Ligands: Remarkably Active Catalysts for the Copolymerization of Ethylene and Carbon Monoxide", Organometallics, vol. 18, 3558-3560, 1999.
Kato et al.,, Macromolecules , 28, 1721, 1995.
Wang et al., Macromolecules , 28, 7572, 1995.
Wang et al., , Macromolecules , 28, 7901, 1995.
Drent et al., Chem. Rev., 1996, 96 663.
Bhaduri et al., Organometallics 1992, 11, pp. 4069-4076.
Quin, Compr. Heterocycl. Chem. II Bird, Clive W. (Ed), 1996, vol. 2, pp. 757-856.
Charrier et al., Organometallics 1987, 6 pp. 586 91.
Gradoz et al., J. Chem. Soc. Dalton Trans. 1992, pp. 3047-3051.
Fagan et al., J. Am. Chem. Soc. 1994, 116, pp. 1880-1889.
Fagan et al., J. Am. Chem. Soc. 1988, 110, pp. 2310-2312.
Neilbecker et al, New J. Chem. 1991, pp. 279-281.
Neilbecker et al., J. Mol. Catal. 1989, 57, pp. 153-163.
Neilbecker et al., J. Mol. Catal. 1989, 219-227.
Vac et al., Inorg. Chem. 1989 28, pp. 3831-3836.
Hjortkjaer et al., J. Mol. Catal. 1989 50, 203-210.
Gouygou et al., Organometallics 1997, 16, 1008-1015.
Granel et al., , Macromolecules , 29, 8576, 1996.
Brubaker, J. Am. Chem. Soc., 74, 1509, 1952.
Steinberg, Polym. Eng. Sci., 17, 335, 1977.

Affiliated with

Also associated with

Rating

Phosphole and diphosphole ligands for catalysis does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Phosphole and diphosphole ligands for catalysis, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Phosphole and diphosphole ligands for catalysis will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1965600