Phosphohemihydrate process for purification of gypsum

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Alkaline earth metal

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423 2, 423 11, 423167, 423319, 423321R, 423555, 423 18, 423 20, 106110, C01F 1146, C01F 1300, C01B 2516, G21F 928

Patent

active

044241968

ABSTRACT:
A wet process for producing phosphoric acid and phosphohemihydrate by acidulation of phosphate rock. A strong phosphoric acid is obtained with concomitant production of an improved calcium sulfate that is extremely low in radioactivity by operation in Region II for shorter time so as to produce small sized hemihydrate particles, then hydration of a substantial proportion but less than all of the hemihydrate to coarse gypsum substantially free of radioactivity in a dilute acidic aqueous slurry at a temperature and P.sub.2 O.sub.5 concentration selected so as to be within Region I of FIG. 1 and having a substantial weight proportion of coarser gypsum particles that are substantially free of radioactivity.

REFERENCES:
patent: 3951675 (1976-04-01), Krempff
patent: 4146568 (1979-03-01), Lange, Jr.
patent: 4282192 (1981-08-01), Larson
patent: 4311677 (1982-01-01), Gerunda et al.

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