Phosphine compounds, transition metal complexes with the...

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus containing

Reexamination Certificate

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C568S017000, C556S016000

Reexamination Certificate

active

06987202

ABSTRACT:
Phosphine compounds represented by the following formula (1):wherein R1, R2, R3, R4, R5, R6and R7represent substituents, and asymmetric synthesis catalysts containing transition metal phosphine complexes with the compounds contained as ligands therein.The novel phosphine compounds according to the present invention are useful especially as ligands in transition metal complexes. The transition metal phosphine complexes are useful as catalysts for asymmetric synthetic reactions. The novel phosphine compounds useful as ligands can be prepared by a relatively economical preparation process. Further, use of these catalysts can afford hydrogenated products with high optically purity and is also extremely useful from the industrial standpoint.

REFERENCES:
patent: 5171892 (1992-12-01), Burk
patent: 5516944 (1996-05-01), Broger et al.
patent: 6-508848 (1994-10-01), None
patent: 7-149777 (1995-06-01), None
patent: 2002-527444 (2002-08-01), None
patent: 2002-527445 (2002-08-01), None
patent: WO 93/01199 (1993-01-01), None
patent: WO 00/21970 (2000-04-01), None
Castro et al. Unexpected Roles of Guest Polarizability and Maximum Hardness, and of Host Solvation in Supramolecular Inclusion Complexes: A Dual Theoretical and Experimental Study.□□Journal of the American Chemical Society, 1996, 118, p. 10257-10268.
R. Noyori, Asymmetric Catalysis In Organic Synthesis, chapter 2, pp. 16-94, “Homogeneous Asymmetric Hydrogenation”, 1994.
J-J. Brunet, et al., Journal of Molecular Catalysis, vol. 72, pp. L21-L25, “Catalytic Asymmetric Hydrogenation Using Rhodium Complexes of Dippop, A Chiral Ligand Bearing Two Phospholyl Moieties”, 1992.
M. Ogasawara, et al., Organometallics, vol. 20, No. 5, pp. 1014-1019, “Synthesis and Characterization of a Novel Chiral Phosphole and its Derivatives”, 2001.
T. Saito, et al., Advanced Synthesis and Catalysis, vol. 343, No. 5, XP-002253903, pp. 264-267, “New Chiral Diphosphine Ligands Designed to have a Narrow Dihedral Angle in the Biaryl Backbone”, Mar. 2001.
J. H. Koh, et al., Organometallics, vol. 21, No. 1, XP-001106865, pp. 7-9, “Disparate Roles of Chiral Ligands and Molecularly Imprinted Cavities in Asymmetric Catalysis and Chiral Poisoning”, Jan. 7, 2002.

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