Phosphazene trimer purification

Chemistry of inorganic compounds – Phosphorus or compound thereof – Halogen containing

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23293R, C01B 2510

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active

046030387

ABSTRACT:
Cyclic phosphonitrilic chloride trimer suitable for polymerization to light colored, high molecular weight, linear polyphosphonitrilic chloride can be made by (1) reacting PCl.sub.5 and NH.sub.4 Cl in an inert solvent (e.g. monochlorobenzene) to form a solution of a low molecular weight linear and cyclophosphonitrilic chlorides, (2) evaporating solvent to form a concentrate, (3) adding water and cooling the mixture to precipitate cyclic trimer, (4) separation of the trimer precipitate and (5) distillation of the separated trimer.

REFERENCES:
patent: 4175113 (1979-11-01), Fieldhouse
patent: 4382914 (1983-05-01), Horie et al.

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