Phosphate and phosphonate compounds including and derived from p

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus esters

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558161, C07F 940

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active

050970577

ABSTRACT:
There are disclosed novel phosphorus-containing compounds including and derived from hydrogen phosphonates. The compounds of the present invention can be prepared by reacting a hydrogen phosphonate with: (a) an ethylene derivative in a Michael reaction, (b) an amine or amide and formaldehyde in a Mannich reaction, (c) an aldehyde or ketone, (d) a halogen, (e) carbon tetrachloride and an alkylamine, and (f) carbon tetrachloride and a hydroxyphosphonate. Halophosphonates produced according to procedure (d) can also be used in reactions with (a) alkylamines and (b) hydroxyphosphonates or epoxides to produce the compounds of the present invention.

REFERENCES:
patent: 3332893 (1967-07-01), Birum et al.
patent: 3391226 (1968-07-01), Birum et al.
patent: 4808744 (1989-02-01), Hardy et al.
patent: 4883891 (1989-11-01), Hardy et al.
patent: 4886895 (1989-12-01), Hardy et al.
Arbuzov et al, Journal of General Chemistry of USSR, 29 p. 2582 (1959) (English Translation).
Abrurzov et al. Chemical Abstracts, vol. 54, No. 10836 (1960).

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