Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1974-08-05
1978-09-12
Helfin, Bernard
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260600R, 252522, C07C 4752
Patent
active
041137817
ABSTRACT:
Substituted phenylpropanals and a process for their manufacture by reaction of the corresponding phenylethenes with carbon monoxide and hydrogen at temperatures of from 50.degree. to 180.degree. C and pressures of from 20 to 1,500 atmospheres gauge, in the presence of rhodium carbonyl complexes. The phenylpropanals according to the invention have pleasant scents. 3-(4-Isopropyl-phenyl)-butanal-1 and 3-(4-tert.-butyl-phenyl)-butanal-1, in particular, have suitable scents for the preparation of flower oil. They are also valuable starting materials for synthesizing drugs, plant protection agents and dyes.
REFERENCES:
patent: 2875131 (1959-02-01), Carpenter et al.
patent: 2880241 (1959-03-01), Hughes
patent: 3555098 (1971-01-01), Olivier et al.
patent: 3801646 (1974-04-01), Booth
Aquila Werner
Himmele Walter
Hoffmann Werner
Siegel Hardo
BASF - Aktiengesellschaft
Helfin Bernard
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