Phenolic developer resins

Recorders – Record receiver deforming

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Details

346211, 346212, 346225, 427150, B41M 522

Patent

active

046479520

ABSTRACT:
Formaldehyde-free resins of the formula (I): ##STR1## where n is an integer greater than or equal to 2, the phenolic units of the resin are directly bonded to one another through positions ortho or para to the hydroxyl group, Y is present at a position meta or para to the hydroxy group and is selected from the group consisting of an alkyl group, a halogen atom, an aryl group, a phenylalkyl group, an allyl group, a carboxyl group of the formula --COOR, where R is a hydrogen atom, an alkyl group or a phenylalkyl group, an amino group of the formula --NR.sub.1 R.sub.2 where R.sub.1 and R.sub.2 are the same or different and represent a hydrogen atom or an alkyl group, and Z is a hydrogen atom, an alkyl group, a halogen atom, an aryl group, a phenylalkyl group, or a --COOR group, or Z in conjunction with the adjacent meta position forms a condensed benzene ring; or a metal-modified, formaldehyde-free phenolic developer resin obtained by reacting said developer resin with a metal salt; the resins are useful as developers in forming colored images by reaction with substantially colorless electron-donating compounds.

REFERENCES:
patent: 3244549 (1966-04-01), Farnham et al.
patent: 3244550 (1966-04-01), Farnham et al.
patent: 4025490 (1977-05-01), Weaver
patent: 4173684 (1979-11-01), Stolfo
"The Oxidation of Phenol and Its Reaction Product by Horseradish Peroxidase and Hydrogen Peroxide", by Dean J. Danner et al., Archives of Biochemistry and Biophysics 156, 759-763 (1973).
"Peroxidase for Removal of Hazardous Aromatics from Industrial Wastewaters", by Barbara N. Alberti et al., Biological Detoxication, 349-356 (1982).
Bollag and Liu, "Copolymerization of Halogenated Phenols and Syringic Acid" Pesticide Biochemistry and Physiology 23, C.261-272 (1985).
Klibanov et al., "Enzymatic Removal of Toxic Phenols and Anilines from Waste Waters", Journal of Applied Biochemistry, 2, pp. 414-421 (1980).
"Biocatalytic Oxidation of Hydroquinone to P-Benzoquinone in a Water-Organic Solvent Two-Phase System", Manjeet Singh et al., Biotechnology Letters, vol. 7, No. 9, 663-664 (1985).

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