Phenol-formaldehyde resins as additives for solution-polymerized

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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524505, 525139, 525901, C08L 6110

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active

044567278

ABSTRACT:
In a process of curing solution-polymerized synthetic rubbers, the improvement effected is the retardation of the cure rate and increasing of time to scorch by the addition of small amounts of a heat-curable phenol-formaldehyde resin. This method of controlling cure rate and scorch time complements other techniques known in the art (e.g., cure accelerators), and can be used to adjust the properties of solution-polymerized rubbers to match those of emulsion-polymerized rubbers.

REFERENCES:
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patent: 2708192 (1955-05-01), Joesting et al.
patent: 2734039 (1956-02-01), Peterson et al.
patent: 3000847 (1961-09-01), Graham
patent: 3250733 (1966-05-01), Giller
patent: 3483017 (1969-12-01), Korpman
patent: 3631143 (1971-12-01), Rizzer
patent: 3746669 (1973-07-01), Dunnom et al.
Hsieh, H. L., "Rubber & Plastics Age" 46, No. 4, 394, 1965; Reprint `Solution Polymerization Initiated with Alkyllithiums`, pp. 1-8.
Robert W. Martin, "The Chemistry of Phenolic Resins", John Wiley & Sons, New York, (1956), pp. 87-136.

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