Phenol alkylation process

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568780, 568790, C07C 3714

Patent

active

047314923

ABSTRACT:
A process of ortho-alkylating arylhydroxides, e.g., phenol, by passing a mixture of arylhydroxide, olefin and an inert hydrocarbon diluent in the liquid phase through a bed of activated alumina at an elevated temperature and pressure. Conversion and selectivity is improved over that obtained without the diluent.

REFERENCES:
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patent: 3290389 (1966-12-01), Hahn
patent: 3367981 (1968-02-01), Napolitano
patent: 3670030 (1972-06-01), Sparks
patent: 3831898 (1958-04-01), Ecke
patent: 4260833 (1981-04-01), Firth
patent: 4599465 (1986-07-01), Tamaru

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