Radiation imagery chemistry: process – composition – or product th – Radiation modifying product or process of making – Radiation mask
Reexamination Certificate
2001-01-11
2003-01-07
Rosasco, S. (Department: 1756)
Radiation imagery chemistry: process, composition, or product th
Radiation modifying product or process of making
Radiation mask
C428S432000
Reexamination Certificate
active
06503668
ABSTRACT:
This invention relates to phase shift mask blanks and phase shift masks for use in the fabrication of semiconductor integrated circuits, and more particularly, to phase shift mask blanks and phase shift masks of the halftone type wherein light of exposure wavelength is attenuated by the phase shift film. It also relates to a method of manufacturing such phase shift mask blanks and phase shift masks.
BACKGROUND OF THE INVENTION
Photomasks are used in a wide variety of applications including the fabrication of semiconductor integrated circuits such as ICs, LSIs and VLSIs. Basically, the photomask is prepared from a photomask blank having a chromium based light-shielding film on a transparent substrate, by forming a predetermined pattern in the light-shielding film by photolithography using UV or electron beams. The current demand for a higher level of integration in the semiconductor integrated circuit market has created a need for a smaller pattern rule. The traditional solution is by reducing the wavelength of exposure light.
However, reducing the wavelength of exposure light improves resolution at the sacrifice of focal depth. This lowers the process stability and adversely affects the manufacture yield of products.
One effective pattern transfer method for solving the problem is a phase shift method. A phase shift mask is used as a mask for transferring a micro-pattern.
Referring to
FIGS. 9A and 9B
, a phase shift mask, specifically a halftone phase shift mask is illustrated as comprising a substrate
32
and a phase shifter
34
forming a pattern on the substrate, the substrate
32
being uncovered where the phase shifter
34
is absent. A phase difference of about 180° is set between light transmitted by the uncovered area of substrate
32
and light transmitted by the phase shifter. Due to light interference at the pattern boundary, the light intensity at the interfering boundary becomes zero, improving the contrast of a transferred image. The phase shift method permits to increase the focal depth for acquiring the desired resolution. This achieves improvements in resolution and exposure process margin, as compared with conventional masks having ordinary light-shielding patterns in the form of chromium film.
Depending on the light transmission of phase shifter, the phase shift masks are generally divided for practical application into full transmission type phase shift masks and halftone type phase shift masks. The full transmission type phase shift masks are transparent to the exposure light wavelength because the light transmittance of the phase shifter section is equal to the light transmittance of uncovered substrate areas. In the halftone type phase shift masks, the light transmittance of the phase shifter section is several percents to several tens of percents of the light transmittance of uncovered substrate areas.
FIGS. 1 and 2
illustrate the basic structure of a halftone type phase shift mask blank and a halftone type phase shift mask, respectively. The halftone type phase shift mask blank shown in
FIG. 1
has a halftone phase shift film formed over substantially the entire surface of a transparent substrate
1
. Patterning the phase shift film
2
results in the halftone type phase shift mask which is shown in
FIG. 2
as comprising phase shifter sections
2
a
forming the pattern on the substrate
1
and uncovered areas
1
a
of the substrate where the phase shifter is absent. Light that passes the phase shifter section
2
a
is phase shifted relative to light that passes the uncovered substrate area
1
a.
The transmittance of the phase shifter section
2
a
is set to a light intensity that is insensitive to the resist on the transferred substrate. Accordingly, the phase shifter section
2
a
has a light-shielding function of substantially shielding exposure light.
The halftone type phase shift masks include single-layer halftone type phase shift masks featuring a simple structure and ease of manufacture. Some single-layer halftone type phase shift masks known in the art have a phase shifter of MoSi base materials such as MoSiO and MoSiON as described in JP-A 7-140635.
What is important for such phase shift masks and phase shift mask blanks is the control of optical properties at the exposure wavelength including transmittance, reflectance and refractive index. In particular, optical properties are largely affected by the film composition.
The phase shift masks and phase shift mask blanks having the molybdenum silicide (MoSi) based phase shifter are generally manufactured by a reactive sputtering technique. The reactive gas used for manufacture often contains oxygen gas or nitrogen monoxide gas as an oxygen source. When MoSiO or MoSiON is deposited as the MoSi based phase shift film using such reactive gas, there arises a problem that optical properties including transmittance, reflectance and refractive index often become non-uniform within the plane of the substrate. This phenomenon occurs because the oxidizing gas such as oxygen gas or nitrogen monoxide gas is so reactive that more reaction takes place near the gas inlet port and the quantity of available gas decreases as it flows away from the gas inlet port. Also because of the high reactivity, optical properties rather become sensitive to variations in gas flow rate, which is undesirable for consistent mass manufacture.
SUMMARY OF THE INVENTION
An object of the invention is to provide a phase shift mask blank and a phase shift mask of quality which has fully uniform optical properties within the plane of the substrate. Another object of the invention is to provide a method for manufacturing a phase shift mask blank and a phase shift mask, which is easy to control during deposition of a phase shift film and enables consistent manufacture.
The invention pertains to a phase shift mask blank comprising a substrate transparent to the wavelength of exposure light and at least one layer of phase shift film on the substrate. It has been found that when the phase shift film is formed of molybdenum silicide oxycarbide or molybdenum silicide oxynitride carbide by a sputtering technique using a target of molybdenum silicide and a sputtering gas containing carbon dioxide as an oxygen source and optionally, nitrogen gas as a nitrogen source, the phase shift film has fully uniform optical properties within the substrate plane. The phase shift mask blank is of quality as well as a phase shift mask obtained from the blank. The method is easy to control during deposition of the phase shift film and enables consistent mass manufacture.
In a first aspect, the invention provides a phase shift mask blank comprising a transparent substrate and at least one layer of a phase shift film on the substrate. The phase shift film is formed of molybdenum silicide oxycarbide or molybdenum silicide oxynitride carbide.
In a second aspect, the invention provides a phase shift mask blank comprising a transparent substrate, at least one layer of phase shift film on the substrate, the phase shift film being formed of molybdenum silicide oxycarbide or molybdenum silicide oxynitride carbide, and a chromium-based light-shielding film, a chromium-based antireflection film or a multilayer combination of both on the phase shift film. The chromium-based light-shielding film or antireflection film is preferably formed of chromium oxycarbide or chromium oxynitride carbide.
In either embodiment, the phase shift film shifts the phase of exposure light passing through it by 180±5 degrees and has a transmittance of 3 to 40%.
In a third aspect, the invention provides a phase shift mask manufactured by patterning the phase shift film on the phase shift mask blank.
In a fourth aspect, the invention provides a method of manufacturing a phase shift mask blank comprising a transparent substrate and at least one layer of phase shift film on the substrate, the method comprising the step of forming the phase shift film by a sputtering technique using a target of molybdenum silicide and a sputtering gas containing carbon dioxide as an oxygen source and o
Inazuki Yukio
Kaneko Hideo
Maruyama Tamotsu
Okazaki Satoshi
Millen White Zelano & Branigan P.C.
Rosasco S.
Shin-Etsu Chemical Co. , Ltd.
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