Pharmaceutical intermediate for synthesizing ACE inhibitors...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C548S452000, C548S493000, C558S263000

Reexamination Certificate

active

07960558

ABSTRACT:
The compounds of the general Formula (I), wherein R1is aryl or alkyl; R2represents alkyl; R3represents alkyl or aralkyl, are valuable pharmaceutical intermediates, which can be prepared by reacting a compound of the general Formula (IV) (wherein the definitions of R1and R2are as above), with at least 2 molar equivalents of the compound of the general Formula (VI) (wherein X represents halogen or tertiary butyloxycarbonyloxy group and R3is as defined above). The known compounds of the general Formula (II) (wherein R1and R2are as defined above) are prepared by reacting the compounds of the general Formula (I) with thionyl chloride. The compounds of the general Formula (I) are new intermediates useful in the synthesis of pharmaceutically active ingredients, particularly in the preparation of ACE-inhibitors, e.g. enalapril, perindopril or ramipril.

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patent: 2004/0248814 (2004-12-01), Cid
patent: 2007/0197821 (2007-08-01), Simig et al.

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