Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Phosphorus containing other than solely as part of an...
Patent
1997-10-09
1999-10-26
Robinson, Allen J.
Drug, bio-affecting and body treating compositions
Designated organic active ingredient containing
Phosphorus containing other than solely as part of an...
514 92, 514 94, 514144, 5142238, A01N 5700, A01N 5710, A61K 3154
Patent
active
059729155
DESCRIPTION:
BRIEF SUMMARY
The present invention relates to a pesticide which comprises an active ingredient combination consisting of ##STR12## and b) O-(O-ethyl-S-n-propylphosphoryl)-O-(N-methylcarbamoyl)pyrocatechol of the formula ##STR13## and/or c) O-ethyl S,S-dipropyl phosphorodithioate of the formula ##STR14## and/or d) 2-methyl-2-methylthiopropionaldehyde O-methylcarbamoyloxime of the formula ##STR15## and/or e) N,N-dimethyl-2-methylcarbamoyloximino-2-methylthioacetamide of the formula ##STR16## and/or f) ethyl-4-methylthio-m-tolylisopropylphosphoramide of the formula ##STR17## and/or g) (RS)-S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphonothioate of the formula ##STR18## and/or h) 2,3-dihydro-2,2-dimethylbenzofuran-7-yl methylcarbamate of the formula ##STR19## and/or i) S-tert-butylthiomethyl O,O-diethyl phosphorodithioate of the formula ##STR20## and/or j) S,S-di-sec-butyl O-ethyl phosphorodithioate of the formula ##STR21## and/or k) (RS)-O-1-(4-chlorophenyl)pyrazol-4-yl O-ethyl S-propyl phosphorothioate of the formula ##STR22## in a synergistically active amount.
The invention additionally relates to methods of controlling pests and to the use of the compound I and one or more of the compounds II to XI for preparing pesticides of this type.
The compound of the formula I (common name dazomet), its preparation and its action against pests are disclosed in the literature (U.S. Pat. No. 2,838,389; WO 93/13085). The compounds of the formulae II to XI, their preparation and their action against pests are also disclosed:
Compound II (EP-B-0309843);
Compound III, common name ethoprophos, (U.S. Pat. Nos. 3,112,244; 3,268,393);
Compound IV, common name aldicarb, (U.S. Pat. No. 3,217,037);
Compound V, common name oxamyl, (U.S. Pat. Nos. 3,530,220; 3,658,870);
Compound VI, common name fenamiphos, (DE 1 121 882); U.S. Pat. No. 2,978,479);
Compound VII, common name fosthiazate, (The Pesticide Manual, 9th Edition, No. 6805);
Compound VIII, common name carbofuran, (DE 1 493 646; U.S. Pat. Nos. 3,474,170; 3,474,171);
Compound IX, common name terbufos, (The Pesticide Manual, 9th Edition, No. 11300);
Compound X, common name cadusafos, (The Pesticide Manual, 9th Edition, No. 1835);
Compound XI, common name pyraclofos, (The Pesticide Manual, 9th Edition, No. 10 335).
With respect to lowering application rates and improving the spectrum of action of the known compounds, the object of the present invention was based on mixtures which, together with a decreased total amount of applied active ingredients, have an improved action against pests (synergistic mixtures).
The compositions defined at the outset were accordingly found. It was additionally found that pests can be better controlled with simultaneous joint or separate application of the compound I and one or more of the compounds II to XI or with application of the compound I and one or more of the compounds II to XI in succession than with the individual compounds.
The pesticides according to the invention are suitable for effectively controlling pests of the insects, arachnids and nematodes classes. They are moreover suitable for effectively controlling harmful soil fungi and phytotoxic soil bacteria, eg. Agrobacterium tumefaciens, and germinating plants. They can be employed as pesticides in crop protection and in the hygiene and stored materials protection sector. They are advantageously used as soil disinfectants.
The harmful insects include from the order of the butterflies (Lepidoptera), for example, Agrotis ypsilon, Agrotis segetum, Alabama argillacea, Anticarsia gemmatalis, Argyresthia conjugella, Autographa gamma, Bupalus piniarius, Cacoecia murinana, Capua reticulana, Cheimatobia brumata, Choristoneura fumiferana, Choristoneura occidentalis, Cirphis unipuncta, Cydia pomonella, Dendrolimus pini, Diaphania nitidalis, Diatraea grandiosella, Earias insulana, Elasmopalpus lignosellus, Eupoecilia ambiguella, Evetria bouliana, Feltia subterranea, Galleria mellonella, Grapholita funebrana, Grapholita molesta, Heliothis armigera, Heliothis virescens, Heliothis zea, Hellula undalis,
REFERENCES:
patent: 2838389 (1958-06-01), Yoder
patent: 3265561 (1966-08-01), Werres et al.
patent: 4855140 (1989-08-01), Seppelt et al.
Worthing et al, The Pesticides Manual, 9th Ed. pp. 225-226 (1991).
Agronomia Columbiana, 1991, vol. 8, No. 2, 248-252.
Derwent Abst. JP 48 038 139 (1973).
Derwent Abst. JP 58 170 706 (1983).
Bratz Matthias
Harries Volker
Hofmeister Peter
Jager Karl-Friedrich
Neumann Ulrich
BASF - Aktiengesellschaft
Robinson Allen J.
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