Drug – bio-affecting and body treating compositions – Preparations characterized by special physical form – Biocides; animal or insect repellents or attractants
Reexamination Certificate
2000-04-07
2002-10-22
Levy, Neil S. (Department: 1616)
Drug, bio-affecting and body treating compositions
Preparations characterized by special physical form
Biocides; animal or insect repellents or attractants
C424S405000, C514S345000, C514S374000
Reexamination Certificate
active
06468555
ABSTRACT:
FILED OF INVENTION
The present invention relates to pesticidal compositions.
BACKGROUND OF THE INVENTION
The development of pesticides has been widely carried out for the control of many kinds of pests including agricultural and forest pests and hygienically unfavorable pests, and a wide variety of chemical agents have been put to practical use. All conventional pesticides, however, cannot be said to give satisfactory results; for example, they may lack at least one of lethal efficacy, immediate effect, and residual effect, or they may have poor results on the specific kinds of pests or on the specific growth stage of pests. Accordingly, there has been a demand for the development of more excellent pesticides.
SUMMARY OF THE INVENTION
Under these circumstances, the present inventors have concentrated on the study and consequently found that pesticidal compositions comprising 4-phenoxyphenyl 2-(2-pyridyloxy)propyl ether and 2-(2,6-difluorophenyl)-4-(2-ethoxy-4-tert-butyl-phenyl)-2-oxazoline as active ingredients, when used to control agricultural and forest pests or hygienically unfavorable pests, can have unpredictably high pesticidal efficacy and exhibit excellent immediate effect and residual effect as compared with the separate application of each compound, making it possible to solve the above problems, which leads to the present invention.
Thus the present invention provides pesticidal compositions (hereinafter referred to as the present compositions) comprising 4-phenoxyphenyl 2-(2-pyridyloxy)propyl ether (hereinafter referred to as compound A) and 2-(2,6-difluorophenyl)-4-(2-ethoxy-4-tert-butyl-phenyl)-2-oxazoline (hereinafter referred to as compound B) as active ingredients; pest control methods comprising application of the present compositions to pests or their habitats; and plant protection methods comprising application of the present compositions to plants or their neighborhood, which may be infested with agricultural and forest pests.
DETAILED DESCRIPTION OF THE INVENTION
The active ingredients in the present compositions are well known in the art; compound A (common name: pyriproxyfen) from U.S. Pat. No. 4,751,225 and compound B (common name: etoxazole) from WO 93/22297.
The present compositions can be applied as control agents against many kinds of pests including agricultural and forest pests and hygienically unfavorable pests. Specific examples of the pests which can be controlled by the present compositions are the following insects, acarines, and nematodes.
Hemiptera
Delphacidae such as
Laodelphax striatellus, Nilaparvata lugens,
and
Sogatella furcifera;
Deltocephalidae such as
Nephotettix cincticeps
and
Nephotettix virescens;
Aphididae such as
Aphis gossypii, Myzus persicae, Aphis citricola, Lipaphis pserudobrassicae, Nippolachnus piri, Toxoptera aurantii,
and
Toxoptera ciidius;
Pentatomidae such as
Nezara antennata, Cletus punctiger, Riptortus clavetus,
and
Plautia stali;
Aleyrodidae such as
Trialeurodes vaporariorum, Bemisia tabaci,
and
Bemisia argentifolii;
Diaspididae such as
Aonidiella aurantii, Comstockaspis perniciosa, Unaspis citri, Pseudaulacaspis pentagons,
and
Lepidosaphes beckii;
Coccidae such as
Saissetia oleae
and
Ceroplastes rubens;
Margarodidae such as
Icerya purchasi;
Tingidae; Psyllidae, etc.
Lepidoptera
Pyralidae such as
Chilo suppressalis, Cnaphalocrocis medinalis, Ostrinia nubilalis, Parapediasia teterrella, Notarcha derogata,
and
Plodia interpunctella;
Noctuidae such as
Spodoptera litura, Pseudaletia separata, Mamestra brassicae, Agrotis ipsilon,
Trichoplusia spp., Heliothis spp., and Helicoverpa spp.; Pieridae such as
Pieris rapae crucivora;
Tortricidae such as Adoxophyes spp.,
Grapholita molesta,
and
Cydia pomonella;
Carposinidae such as
Carposina niponensis;
Lyonetiidae such as Lyonetia spp.; Lymantriidae such as Lymantria spp. and Euproctis spp.; Yponomeutidae such as
Plutella xylostella;
Gelechiidae such as
Pectinophora gossypiella;
Arctiidae such as
Hyphantria cunea;
Tineidae such as
Tinea translucens
and
Tineola bisselliella,
etc.
Diptera
Calicidae such as
Culex pipiens pallens
and
Culex tritaeniorhynchus;
Aedes spp. such as
Aedes aegypti
and
Aedes albopictus;
Anopheles spp. such as
Anopheles sinensis;
Chironomidae; Muscidae such as
Musca domestica
and
Muscina stabulans;
Calliphoridae; Sarcophagidae; Finnia spp.; Anthomyiidae such as
Delia platura
and
Delia antiqua;
Tephritidae; Drosophilidae; Psychodidae; Simuliidae; Tabanidae; Stomoxyinae; Agromyzidae, etc.
Coleoptera
Diabrotica spp. such as
Diabrotica virgifera virgifera
and
Diabrotica undecimpunctata howardi;
Scarabaeidae such as
Anomala cuprea
and
Anomala rufocuprea;
Curculionidae such as
Sitophilus zeamais, Lissorhoptrus oryzophilus, Hypera pastica,
and
Callosobruchuys chienensis;
Tenebrionidae such as
Tenebrio molitor
and
Tribolium castaneum;
Chrysomelidae such as
Aulacophora femoralis, Phyllotreta striolata,
and
Leptinotarsa decemlineata;
Anobiidae; Epilachna spp. such as
Epilachna vigintioctopunctata;
Lyctidae; Bostrychidae; Cerambycidae;
Paederus fuscipes
, etc.
Dictyoptera
Blattella germanica, Periplaneta fuliginosa, Periplaneta americana, Periplaneta brunnea, Blatta orientalis,
etc.
Thysanoptera
Thrips palmi, Thrips tabaci, Thrips hawaiiensis, Scirtothrips dorsalis, Frankliniella intonsa, Frankliniella occidentalis, Ponticulothrips diospyrosi,
etc.
Hymenoptera
Formicidae, Vespidae, Bethylidae, Tenthredinidae such as
Athalia japonica,
etc.
Orthoptera
Gryllotalpidae, Acrididae, etc.
Aphaniptera
Ctenocephalides felis, Ctenocephalides canis, Purex irritans
, etc.
Anoplura
Pediculus humanus corporis, Phthirus pubis,
etc.
Isoptera
Reticulitermes speratus, Coptotermes formosanus,
etc.
Acarina
Tetranychidae such as
Tetranychus urticae, Tetranychus kanzawai, Panonychus citri, Panonychus ulmi,
and Oligonychus spp.; Eriophyidae such as
Aculops pelekassi
and
Calacarus carinatus,
Tarsonemidae such as
Polyphagotarsonemus latus;
Tenuipalpidae; Tuckerellidae; Ixodidae such as
Haemaphysalis japonica, Haemaphysalis flava, Haemaphysalis Longicornis, Boophilus microplus, Ixodes ovatus,
and
Ixodes persulcatus;
Acaridae such as
Tyrophagus putresceutiae;
Epidermoptidae such as
Dermatophagoides farinae
and
Dermatophagoides ptrenyssnus;
Cheyletidae such as
Cheyletus eruditus, Cheyletus fortis, Cheyletus malaccensis,
and
Cheyletus moorei;
Dermanyssidae, etc.
Nematoda
Pratylenchus coffeae, Pratylenchus fallax, Pratylenchus loosi, Pratylenchus vulnus, Heterodera glycines, Globodera rostochiensis, Meloidogyne hapla, Meloidogyne incognita,
etc.
The present compositions, although they may consist of compound A and compound B, can be made suitable for practical use by allowing various solid, liquid, or gaseous carriers to hold the present compositions, to which surfactants, dispersants, fixing agents, stabilizers, propellants, or other auxiliaries are added, if necessary, followed by formulation into various forms including oil sprays, emulsifiable concentrates, wettable powders, flowables such as aqueous suspensions and aqueous emulsions, microcapsule formulations, spot-on or pour-on formulations, shampoo formulations, granules, dusts, aerosols, ULV agents, poison baits, sheet-shaped formulations, and resin formulations.
The solid carrier which can be used in the formulation may include, for example, fine powder or granules of clay materials such as kaolin clay, diatomaceous earth, synthetic hydrated silicon oxide, bentonite, Fubasami clay, and acid clay; various kinds of talc, ceramics, and other inorganic minerals such as sericite, quartz, sulfur, activated carbon, calcium carbonate, and hydrated silica; and chemical fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, and ammonium chloride.
The liquid carrier may include, for example, water; alcohols such as methanol and ethanol; ketones such as acetone and methyl ethyl ketone; aromatic hydrocarbons such as benzene, toluene, xylene, ethylbenzene, and methylnaphthalene; aliphatic hydrocarbons
Birch Stewart Kolasch & Birch, LLP.
Levy Neil S.
Sumitomo Chemical Company Limited
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