Peroxidic complexes of vanadium, niobium and tantalum, used as r

Details Peroxidic complexes of vanadium, niobium and tantalum, used as r Peroxidic complexes of vanadium, niobium and tantalum, used as r

1983-06-21

1985-07-16

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568741, 568771, C07C 3760, C07C 3904

Patent

active

045298246

ABSTRACT:
Peroxidic complexes of vanadium, niobium or tantalum, wherein the metal is linked to an oxygen molecule carrying two negative charges, are used either as reactants for the oxidation of olefinic substrates or hydrocarbons, or as hydrocarbons oxidation catalysts, particularly for converting olefinic compounds to epoxides or aliphatic or aromatic hydrocarbons to the corresponding alcohols or phenols.

REFERENCES:
patent: 2395633 (1946-02-01), Milas
patent: 2437648 (1948-03-01), Milas
patent: 3488395 (1970-01-01), Hooper
patent: 3662006 (1972-05-01), Maisse et al.
Funahashi et al. "Inorganic Chemistry " vol. 16, (1977) pp. 1349-1353.
Milas, "J. Amer. Chem. Soc." vol. 59 (1937) pp. 2342-2344.

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