Perovskite-type metal oxide compounds and methods of making...

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Mixture is exhaust from internal-combustion engine

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C423S213500, C423S239100, C423S247000

Reexamination Certificate

active

07014825

ABSTRACT:
Perovskite-type catalyst consists essentially of a metal oxide composition and methods of using them are provided. The metal oxide composition is represented by the general formula Aa−xBxMOb, in which A is a mixture of elements originally in the form of single phase mixed lanthanides collected from bastnasite; B is a divalent or monovalent cation; M is at least one element selected from the group consisting of elements of an atomic number of from 23 to 30, 40 to 51, and 73 to 80; a is 1 or 2; b is 3 when a is 1 or b is 4 when a is 2; and x is a number defined by 0≦x<0.5. Methods of making and using the perovskite-type catalysts are also provided. The perovskite-type catalyst may be used to reduce nitrogen oxides, oxidize carbon monoxide, and oxidize hydrocarbons in an exhaust stream from a motor vehicle. Methods of such a use are provided.

REFERENCES:
patent: 3865752 (1975-02-01), Remeika et al
patent: 3865923 (1975-02-01), Stephens
patent: 3884837 (1975-05-01), Remeika et al.
patent: 3897367 (1975-07-01), Lauder
patent: 3929670 (1975-12-01), Kudo et al.
patent: 4001371 (1977-01-01), Remeika et al.
patent: 4049583 (1977-09-01), Lauder
patent: 4107163 (1978-08-01), Donohue
patent: 4126580 (1978-11-01), Lauder
patent: 4127510 (1978-11-01), Harrison et al.
patent: 4151123 (1979-04-01), McCann, III
patent: 4314996 (1982-02-01), Sekido et al.
patent: 4601883 (1986-07-01), Sekido et al.
patent: 4742038 (1988-05-01), Matsumoto
patent: 4748143 (1988-05-01), Tabata
patent: 4892862 (1990-01-01), Ogushi et al.
patent: 4921829 (1990-05-01), Ozawa et al.
patent: 5318937 (1994-06-01), Jovanovic et al.
patent: 5380692 (1995-01-01), Nakatsuji et al.
patent: 5432024 (1995-07-01), Soma et al.
patent: 5489483 (1996-02-01), Soma et al.
patent: 5622680 (1997-04-01), Monceaux et al.
patent: 5624542 (1997-04-01), Shen et al.
patent: 5686198 (1997-11-01), Kuo et al.
patent: 5932146 (1999-08-01), Kuo et al.
patent: 6165431 (2000-12-01), Mackay et al.
patent: 6531425 (2003-03-01), Golden
patent: 0468127 (1992-01-01), None
patent: 0 641 749 (1995-03-01), None
patent: 5-76762 (1993-03-01), None
patent: 5-154384 (1993-06-01), None
Marcilly et al., Preparation of Highly Dispersed Mixed Oxides and Oxide Solid Solutions by Pyrolysis of Amorphous Organ Precursors,J. Am. Ceram. Soc., 53 (1970) 560, no month.
Libby, Promising Catalyst for Auto Exhaust,Science, 171 (1971) 499, no month.
Voorhoeve et al., Rare-Earth Oxides of Manganese and Cobalt Rival Platinum for the Treatment of Carbon Monoxide in Auto Exhaust,Science, 177 (Jul., 1972) 353.
Voorhoeve et al., Rare-Earth Manganites: Catalysts with Low Ammonia Yield in the Reduction of Nitrogen Oxides,Science180 (Apr., 1973).
Voorhoeve et al., Perovskite Oxides: Materials Science in Catalysis,Science, 195 (Mar., 1977) 827.
Voorhoeve et al., Exploration of Persovskite-Like Catalysts,Mat. Res. Bull., 9 (1974) 655, no month.
Johnson et al., Preparation of High Surface Area Substituted LaMnO3Catalysts,Ceramic Bulletin, 55 (1976) 520, no month.
Baythoun et al., Production of strontium-substituted lanthanum manganite perovskite powder by the amorphous citrate process,J. Mat. Sci., 17 (1982) 2757, no month.
Asamitsu, A structural phase transition induced by an external magnetic field,Nature, 373 (Feb., 1995) 407.
Chakraborty et al., Low-temperature systhesis of ultrafine La0.84 MnO3powder by an autoignition process,J. Mat. Res., 9 (1994) 986, no month.
Kilbourn, B.T., Lanthanides and Yttrium (Raw Materials for Advanced and Engineered Ceramics),Cer. Eng. Sc. Proc.By,—(1985) pp. 1331-1341, no month.
Habashi, F., The Discovery and Industrialization of the Rare Earths, UNOCAL76MOLYCORP, (1994), reprinted from CIM Bulletin Jan. and Feb., 1994.
Sakaguchi et al, Electrocatalytic Activity and Oxygen Adsorption Property of Perovskite-type Oxides,Electrochimica Acta, 35 (1990) 65, no month.
Meadowcroft, D.B., Low-cost Oxygen Electrode Material,Nature, 226 (1970) 847, no month.
Johnson et al., Studies of some Perovskite Oxidation Catalysts Using DTA Techniques,Thermochimica Acta,7 (1973) 303, no month.
Tseung et al, Preparation and Characterization of High Surface Area Semiconducting Oxides,J. Mater. Sci., 5 (1970) 604, no month.
Ni, Yunxiang et al, The atomic arrangement of bastnasite-(Ce), Ce (CO3)F, and structural elements of synchysite-(Ce), rontgenite-(Ce), and parisite-(Ce),Am. Mineral., 78 (1993) 415, no month.
M. Fleischer, Relative Proportions of the Lanthanides in Minerals of the Bastnaesite Group,Can. Mineral, 16 (1978) 361, no month.
Ohbayashi et al., Crystallographic, Electric and Thermochemical Properties of the Perovskite-Type Ln1-xSrxCoO3(Ln: Lanthanoid Element),Japanese Journal of Applied Physics, vol. 13, No..1, Jan. 1974, 1-7.
Taylor, Automobile Catalytic Converters,Springer-Verlag., 1984, pp. 4, 5, 11, no month.
Heck and Farrauto, Automobile Catalysts,Automotive Engineering, Feb. 1996, 93-96.
Narula et al., Materials Chemistry Issues Related to Advanced Materials Applications in the Automotive Industry,Chem. Mater, vol. 8, No. 5, 1996, 984-1003, no month.
Voorhoeve et al., Defect Chemistry and Catalysis in Oxidation and Reduction Over Perovskite-Type Oxides,Annals New York Academy of Science, 1976, pp. 3-21, no month.
Viswanathan, CO Oxidation and NO Reduction on Perovskite Oxides,Catal. Rev.-Sci. Eng., 34(4), 337-354 (1992), no month.
Burton & Garten,Advanced Materials in Catalysis, Academic Press, New York, 1997, no month.
Nakamura et al., Reduction-Oxidation and Catalytic Properties of La1-xSrxCoO3,Journal of Catalysis, 83, 151-159 (1983), no month.
Nitadori & Misono, Catalytic Properties of La1-x, A′xFeO3(A′ = Sr1Ce) and La1-xCexCoO3,Journal of Catalysis, 93, 459-466 (1985), no month.
Nitadori et al., Catalytic Properties of La1-x, A'xMnO3(A' = Sr1Ce, Hf),Journal of Catalysis, 98, 221-228 (1986), no month.
Kirk-Othmer,Encyclopedia of Chemical Technology, 3ed., vol. 19, 833-838 (1982), no month.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Perovskite-type metal oxide compounds and methods of making... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Perovskite-type metal oxide compounds and methods of making..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Perovskite-type metal oxide compounds and methods of making... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3536816

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.