Permreactor and separator type fuel processors for...

Chemistry of inorganic compounds – Carbon or compound thereof – Oxygen containing

Reexamination Certificate

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C423S648100, C423S650000, C423S651000, C423S652000

Reexamination Certificate

active

06919062

ABSTRACT:
Overall permreactor-separator process designs and effective permreactor designs with increased mass and heat transfer, reactant conversion, product yield and optional recycling for processing methane, hydrocarbons, alcohols, carbon monoxide, natural gas, acidic natural gas, cool gas, biomass gas, and mixtures of hydrocarbons with carbon dioxide, based on the reforming reactions of these feedstocks with steam and carbon dioxide and the dehydrogenation reactions of saturated hydrocarbons. Final exit streams from these gas phase processors contain pure hydrogen, hydrogen and carbon monoxide mixture, hydrogen and carbon dioxide mixture, and can be used as a direct feed in molten carbonate, solid oxide, proton exchange membrane, alkaline, phosphoric acid and other types of hydrogen driven fuel cells. Same final exit processed streams can be alternatively used for direct chemical synthesis such as methanol, for hydrogenations and hydrogen based reduction reactions such as those of unsaturated hydrocarbons to paraffins, and as feed in power generation systems such as gas turbines and gas engines.

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Alternative generation of H2, CO and H2, CO2mixtures from steam-carbon dioxide reforming of methane and the water gas shift with permeable (membrane) reactors, S. Vasileiadis et al.,Chem. Eng. Comm., vol. 176, pp. 247-252, (1999).
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Polymer membrane reactors for enhanced hydrocarbon conversion and upgrading, S. Vasileiadis and Zoe Ziaka, Invention Disclosure Document #414880, marked Mar. 6, 1997.

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