Chemistry: electrical and wave energy – Apparatus – Electrolytic
Reexamination Certificate
2007-07-10
2007-07-10
Bell, Bruce F. (Department: 1746)
Chemistry: electrical and wave energy
Apparatus
Electrolytic
C521S027000, C210S500100, C210S500360, C210S500380
Reexamination Certificate
active
09889574
ABSTRACT:
The present invention relates to a permeable membrane diaphragm of different layers for electrolytic cell, especially for chloro-alkali electrolytic cell. The diaphragm is asymmetric, which comprises at least two layers: a flow-controlling permeable layer comprising micro-porous fluoropolymer, especially PTFE, and a diffusion-restricting permeable layer comprising porous film, sheet or cloth made of anticorrosive materials, preferably polypropylene. The flow-controlling layer is mounted near the anode, and the diffusion-restricting layer is mounted near the cathode. The mean pore diameter of the diffusion-restricting layer is at least 5 times more than that of the flow-controlling layer and the thickness of the diffusion-restricting layer is at least 1 times more than that of the flow-controlling layer. The pore diameter of said flow-controlling layer ranges from 0.1–2.0 μm, and its thickness is 0.03–0.2 mm. The pore diameter of said diffusion-restricting layer ranges from 5–50 μm, and its thickness is 0.3–2 mm. The above two layers can also be made of more than one similar thinner membranes respectively.
REFERENCES:
patent: 4921587 (1990-05-01), Dong et al.
patent: 5183545 (1993-02-01), Branca et al.
Bell Bruce F.
Davidson Davidson and Kappel LLC
Harbin Huaer Chemical Company, Ltd.
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