Periodic mesoporous phosphorus-nitrogen compounds

Details Periodic mesoporous phosphorus-nitrogen compounds Periodic mesoporous phosphorus-nitrogen compounds

2008-05-23

2010-11-02

Wyszomierski, George (Department: 1793)

Chemistry of inorganic compounds

Phosphorus or compound thereof

Nitrogen containing

C423S304000, C423S385000, C423S406000, C423S413000

Reexamination Certificate

active

07824641

ABSTRACT:
Provided herein is a new material, periodic mesoporous phosphorus-nitrogen compound, which may be used in a variety of emerging technologies. Its surface properties render it promising as a component in a variety of applications, including gas separation and purification systems in which waste gases such as SO2, SO3, or CO2are separated from other gases. It may also be used as an interlayer dielectric in microelectronic chips. Its structure and composition are useful due to an advantageous and favorable combination of thermal stability, elastic modulus, and dielectric properties. The surface properties and the regularity of the pores furthermore provides utility as shape selective base catalysts. Protonated forms of the material are expected to be useful as a solid acid, and in applications such as acid catalysis. Additionally, because of the thermal behavior of the material, it is useful as “hard” template for other porous materials, without the need of an external reagent.

REFERENCES:
patent: 3931039 (1976-01-01), Yamashita et al.
patent: 3964812 (1976-06-01), Turnbull
patent: 3972838 (1976-08-01), Yamashita et al.
patent: 4025464 (1977-05-01), Yamashita et al.
patent: 4741971 (1988-05-01), Beck et al.
patent: 4766229 (1988-08-01), Kobayashi et al.
patent: 5370853 (1994-12-01), Schnick et al.
patent: 5580921 (1996-12-01), Stepp et al.
patent: 6475663 (2002-11-01), Mohwald et al.
patent: 6746803 (2004-06-01), Bauer et al.
patent: 6932959 (2005-08-01), Sterte et al.
patent: 7071139 (2006-07-01), Gole
patent: 7186460 (2007-03-01), Winkler et al.
patent: 7241502 (2007-07-01), Anselmann et al.
patent: 7291394 (2007-11-01), Winkler et al.
patent: 2004/0035751 (2004-02-01), Plee
Kim et al, “Phosphazenium chloride catalysts immobilized on SBA-15 mesoporous material and silica gel: new exceptionally active catalysts for the chlorination of organic acids.” Chemical Communications, 2003, pp. 372-373.
Wang et al. “Hexagonally ordered mesoporous phosphates oxynitrides.” Microporous and Mesoporous Materials 107, pp. 233-239. Available online Mar. 14, 2007.
Q. Guo et al., Large-Scale Synthesis of Amorphous Phosphorus Nitride Imide Nanotubes with High Luminescent Properties, J. Mater. Res, Feb. 2005, 325-330, vol. 20, No. 2, Materials Research Society.
F. Kleitz et al., Phase Domain of the Cubic Im3m Mesoporous Silica in the EO106PO70EO106-Butanol-H20 System, Langmuir, 2006, 440-445, vol. 22, No. 1, American Chemical Society.
B. Hatton et al., Materials Chemistry for Low-k Materials, Materials Today, Mar. 2006, 22-31, vol. 9, No. 3, Elsevier Ltd.
P. Dibandjo et al., Synthesis of Boron Nitride with a Cubic Mesostructure, Microporous and Mesoporous Materials, 92, 2006, 286-291, Elsevier Inc.
G. Attard et al., Liquid Crystal Phase Templated Mesoporous Platinum Alloy, Microporous and Mesoporous Materials, 44-45, 2001, 154-163, Elsevier Science B.V.
M. MacLachlan et al., Non-Aqueous Supramolecular Assembly of Mesostructured Metal Germanium Sulphides from (Ge4S10)4- Clusters, Nature, Feb. 1999, 681-684, vol. 397, Macmillan Magazines Ltd.
G. Armatas et al., Hexagonal Mesopurous Germanium, Science, Aug. 2006, 817-820, vol. 313, www.sciencemag.org.
K. Landskron et al., Multianvil Synthesis, X-ray Powder Diffraction Analysis, 31P-MAS-NMR, and FTIR Spektroscopy as well as Material Properties of γ-P3N5, a High-Pressure Polymorph of Binary Phosphorus(V) Nitride, Built up from Disorted PN5 Square Pyramids and PN4 Tetrahedra, Z. Anorg. Allg. Chem., 2002, 1465-1471, vol. 628, Wiley-VCH.
A. Lu et al., Nanocasting: A Versatile Strategy for Creating Nanostructured Porous Materials, Adv. Mater, 2006, 1793-1805, vol. 18, Wiley-VCH.
P. Dibandjo et al., Comparison Between SBA-15 Silica and CMK-3 Carbon Nanocasting for Mesoporous Boron Nitride Synthesis, J. Mater Chem., 2005, 1917-1923, vol. 15, The Royal Society of Chemistry.
T. Kim et al., Tailoring the Pore Structure of SBA-16 Silica Molecular Sieve Through the Use of Copolymer Blends and Control of Synthesis Temperature and Time, J. Phys. Chem. B, 2004, 11480-11489, vol. 108, American Chemical Society.
S. Jun et al., Synthesis of New, Nanoporous Carbon with Hexagonally Ordered Mesostructure, J. Am. Chem. Soc., 2000, 10712-10713, vol. 122, American Chemical Society.
Y.Hirota et al., Chemical Vapor Deposition and CHaracterization of Phosphorus-Nitride (P3N5) Gate Insulators for InP Metal-Insulator-Semiconductor Devices, J. Appl. Phys. Jul. 1982, 5037-5043, vol. 53, No. 7, American Institute of Physics.
T. Kim et al, Characterization of Mesoporous Carbons Synthesized with SBA-16 Silica Template, J. Mater. Chem., 2005, 1560-1571, vol. 15, The Royal Society of Chemistry.
P. Dibandjo et al., Synthesis of Boron Nitride with Ordered Mesostructure, Adv. Mater., 2005, 571-574, vol. 17, No. 5, Wiley-VCH.
F. Goettmann et al., Metal-Free Activation of CO2 by Mesoporous Graphite Carbon Nitride, Angew. Chem. Int. Ed., 2007, 2717-2720, vol. 46, Wiley-VCH.
S. Horstmann et al., Synthesis and Crystal Structure of Phosphorus(V) Nitride x-P3N5, Angew. Chem. Int. Ed. Engl., 1997, 1873-1875, vol. 36, No. 17, Wiley-VCH.
M. Markham et al., Birefringent Cadmium-Telluride-Based Metamaterial, Applied Physics Letters, 2005, 011912, vol. 86, American Institute of Physics.
Z. Meng et al., Microtubes and Balls of Amorphous Phosphorus Nitride Imide (HPN2) Prepared by a Benzene-Thermal Method, Chem. Commun., 2001, 469-470, The Royal Society of Chemistry.
W. Schnick et al., Phosphorus Nitride P3N5: Synthesis, Spectroscopic, and Electron Microscopic Investigations, Chem. Mater., 1996, 281-286, vol. 8, American Chemical Society.
S. Kaskel et al., Synthesis, Characterization, and Catalytic Properties of High-Surface-Area Aluminum Silicon Nitride Based Materials, Chem. Mater., 2005, 181-185, vol. 17, American Chemical Society.
Z. Meng, et al., Synthesis and Characterization of Amorphous Phosphorus Nitride, Chemistry Letters, 2000, 1252-1253, The Chemical Society of Japan.
S. Levchik et al., Phosphorus Oxynitride: A Thermally Stable Fire Retardant Additive for Polyamide 6 and Poly (butylene terephthalate), Die Angewandte Makromolekulare Chemie, 1999, 48-55, vol. 264, Wiley-VCH.
M. Kaperman et al., Ordered Mesoporous Ceramics Stable up to 1500 C from Diblock Copolymer Mesophases, J. Am. Chem. Soc., 2004, 14708-14709, vol. 126, American Chemical Society.
D. Zhao et al., Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores, Science, Jan. 1998, 548-552, vol. 279, www.sciencemag.org.
C. Kresge et al., Ordered Mesoporous Molecular Sieves Synthesized by a Liquid-Crystal Template Mechanism, Nature, Oct. 1992, 710-712, vol. 359, Nature Publishing Group.
“amide” and “imide” as defined in “IUPAC Recommendations on the Nomenclature of Inorganic Chemistry,” in Inorganic Chemistry: Principles of Structure and Reactivity, 4th Ed., by Huheey et al., pp. 53, 57 (1993, HarperCollins).
“oxy” as defined in Nomenclature of Inorganic Chemistry, IUPAC Recommendations 2005, pp. 121, 256 (2005, International Union of Pure and Applied Chemistry).

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