Perfumant cyclopropane-carboxylic acid derivatives

Details Perfumant cyclopropane-carboxylic acid derivatives Perfumant cyclopropane-carboxylic acid derivatives

1982-01-27

1984-02-14

Waltz, Thomas A.

Compositions

Electrically conductive or emissive compositions

Metal compound containing

25217411, 424 47, 424 49, 424 69, 424 70, 424 76, 260464, 560124, 549 66, 549323, A61K 746, C11B 900

Patent

active

044315767

ABSTRACT:
A compound in all its possible isomeric forms and mixtures thereof of the formula ##STR1## wherein R is selected from the group consisting of (a) alkyl of 1 to 12 carbon atoms optionally substituted with cycloalkyl or cycloalkenyl of 3 to 6 carbon atoms or a hydrocarbon chain of 2 to 8 carbon atoms optionally interrupted by an oxygen or ketone, (b) alkenyl and alkynyl of 3 to 8 carbon atoms, (c) cycloalkyl of 3 to 12 carbon atoms optionally containing at least one double bond and substituted with at least one alkyl and (d) aralkyl of 7 to 12 carbon atoms optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, halogen and --CF.sub.3 and R.sub.1 and R.sub.2 are individually selected from the group consisting of hydrogen, --CHO, --COAlK.sub.1, --COOAlK.sub.2 and --CN, at least one being hydrogen, AlK.sub.1 and AlK.sub.2 are alkyl of 1 to 8 carbon atoms and R.sub.1 and R.sub.2 taken together with the carbon atom to which they are attached form the group ##STR2## and X is selected from the group consisting of sulfur, oxygen and imino joined to the 1-carbon atom with a double bond with the proviso that the double bond has the E geometry when R.sub.1 or R.sub.2 are --CHO, --COAlK.sub.1, --COOAlK.sub.2 or ##STR3## and their preparation and odorant compositions containing at least one compound of formula I as a perfume agent.

REFERENCES:
patent: 3766218 (1973-10-01), Ueda et al.
patent: 4217300 (1980-08-01), Lantzsch
patent: 4299967 (1981-11-01), Dingwall et al.
patent: 4310540 (1982-01-01), Lantzsch et al.
patent: 4327109 (1982-04-01), Mizutani et al.
patent: 4335252 (1982-06-01), Engel
Perfume and Flavor Chemicals, vol. I, No. 1187, Arctander (1969).
Kondo et al., CA 85: 78225b (1976).
Elliott et al., CA 82: 155439s (1975).
Nagase et al., CA 84: 179749k (1976).

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