Perfluoropolyoxyalkylene endowed with a high viscosity and a low

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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560302, 20415792, C07C40900

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active

053549228

ABSTRACT:
Peroxy perfluoropolyoxyalkylenes are prepared with high yields by carrying out the photo-oxidation of tetrafluoroethylene with molecular oxygen, by means of ultraviolet radiations, operating in the presence of pentafluorochloroethane as a solvent for tetrafluoroethylene.
Thus, it is possible to obtain peroxy perfluoropolyoxyalkylenes having a viscosity at 20.degree. C. ranging from 300,000 to 8,000,000 cSt and endowed with a peroxide content not higher than 4.
Such perfluoropolyoxyalkylenes provide, through chemical reduction, perfluoropolyoxyalkylenes endowed with a functionality higher than 1.9 and at the same time with a high molecular weight.

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