Perfluorodioxole and its polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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528392, C08F 1418, C08F 1422, C08F 1426

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active

043992641

ABSTRACT:
Perfluoro-1,3-dioxole is a useful monomer, which polymerizes to either amorphous or liquid homopolymers and copolymerizes with tetrafluoroethylene as well as with other monomers to both crystalline and amorphous copolymers having one or more such comonomers incorporated therein. Amorphous homopolymers and copolymers of perfluoro-1,3-dioxole are useful in such applications as glazing for reactors for hydrogen fluoride reactions. Amorphous homopolymers and amorphous or crystalline copolymers form self-supporting films and can be used for coatings and linings which are inert to most chemicals and are stain and weather resistant and as dielectrics for electrical and electronic equipment. Liquid homopolymers can be used as hydraulic fluids and heat exchange media.

REFERENCES:
patent: 3308107 (1967-03-01), Selman et al.
patent: 3734862 (1973-03-01), Maulding
patent: 3978030 (1976-08-01), Resnick
D. D. Denjon et al., Preparation and Evaluation of Some New Fluorinated Volatile Anesthetics, pp. 190-208 in ACS Symposium Series 28, Biochemistry Involving Carbon-Fluorine Bonds (Washington, D.C. 1976).
D. R. Maulding et al., The Chemiluminescence of Tetrachloroethylene Carbonate and related compounds, J. Org. Chem., vol. 37, No. 9 (1972), pp. 1458-1459.

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