Perfluorocyclobutane ring-containing polymers with crosslinking

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526243, 526245, 526248, 526250, 526251, 526252, 526253, 526255, 526247, 528 86, 568669, C06F 1418

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050379186

ABSTRACT:
A crosslinked polymer having perfluorocyclobutane rings is prepared in a process comprising the steps of: (a) contacting monomers having two dimerizable perfluorovinyl groups; (b) exposing the monomers to sufficient heat and for a sufficient time that a (linear) polymer containing perfluorocyclobutane rings is formed; and (c) exposing the polymer to sufficient crosslinking initiating means and for a sufficient time such that crosslinking occurs. Crosslinked polymers, so prepared are novel and have tensile strength and other physical proeprties enhanced over the properties of the corresponding linear polymer.

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