Perfluorocarbon polymer oxidation catalyst and preparation of ca

Details Perfluorocarbon polymer oxidation catalyst and preparation of ca Perfluorocarbon polymer oxidation catalyst and preparation of ca

1985-09-17

1986-10-14

Reamer, James H.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

562538, 568485, 568486, 568487, 568426, C07C 51285, C07C 4529

Patent

active

046171533

ABSTRACT:
This invention deals with the use of a perfluorocarbon polymer oxidation catalyst consisting of a perfluorocarbon main chain and a side chain constructed from structural units of chromium (III) difluoromethylene sulfonate or cerium (IV) difluoromethylene sulfonate in a method of preparing a carbonyl compound through an oxidation of an alcohol.

REFERENCES:
patent: 2861045 (1958-11-01), Langer
patent: 3840566 (1974-10-01), Lalancette
patent: 4179403 (1979-12-01), Kim et al.
patent: 4338269 (1984-03-01), Guziec
patent: 4480135 (1984-10-01), Esposito et al.
Frechet et al., J. Org. Chem.; vol. 43, pp. 2618-2621 (1978).

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