Perfluorocarbon polymer oxidation catalyst and preparation of ca

Details Perfluorocarbon polymer oxidation catalyst and preparation of ca Perfluorocarbon polymer oxidation catalyst and preparation of ca

1985-02-11

1986-10-21

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568342, 568385, 568322, 568361, 568404, C07C 4529

Patent

active

046187243

ABSTRACT:
This invention deals with the use of a perfluorocarbon polymer oxidation catalyst consisting of a perfluorocarbon main chain and a side chain constructed from structural units of chromium (III) difluoromethylene sulfonate or cerium (IV) difluoromethylene sulfonate in a method of preparing a carbonyl compound through an oxidation of an alcohol.

REFERENCES:
patent: 2444924 (1948-07-01), Farkas et al.
patent: 2861045 (1958-11-01), Langer
patent: 4179403 (1979-12-01), Kim et al.
patent: 4426534 (1984-01-01), Guziec
patent: 4438269 (1984-03-01), Guziec
patent: 4480135 (1984-10-01), Esposito et al.
Frechet et al, J. Org. Chem., vol. 43, pp. 2618-2621 (1978).

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