Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1988-10-17
1991-02-05
Stoll, Robert L.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568932, 568927, 568936, 570146, C07C20506
Patent
active
049906992
ABSTRACT:
Despite the instabity of perfluoralkyl anions, it is possible to perfluoroalkylate aromatic compounds if appropriately substituted by suitable electronegative substituents (e.g., nitro, trifluoromethylsulfonyl, etc.). Thus a novel Meisenheimer complex is formed by thermally decomposing a salt of a perfluoroalkanoic acid in the presence of an aromatic compound such as 1,3,5-trinitrobenzene. Oxidation with organic hypochlorite yields the corresponding perfluoroalkylated aromatic compound.
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Ethyl Corporation
Fee Valerie
Hammond Richard J.
Sieberth John F.
Stoll Robert L.
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